Spectra for:
Matthias Helms, Wolfgang Schade, Robert Pulz, Toshiko Watanabe, Ahmed Al-Harrasi, Lubor Fišera, Iva Hlobilová, Gernot Zahn, Hans-Ulrich Reißig
Compound ANTI/ANTI-29 (3S,3'S,4''R,5''R)-3-(2'',2''-DIMETHYL-1'',3''-DIOXOLAN-4'',5''-YL)-BIS-(4-METHOXY-2-METHYL-3,6-DIHYDRO-2H-1,2-OXAZINE)
Compound SYN/SYN-29 (3R,3'R,4''R,5''R)-3-(2'',2''-DIMETHYL-1'',3''-DIOXOLAN-4'',5''-YL)-BIS-(4-METHOXY-2-METHYL-3,6-DIHYDRO-2H-1,2-OXAZINE)
Compound 1 1-SYN (3S,4'S)-2-BENZYL-3-(2',2'-DIMETHYL-1',3'-DIOXOLAN-4'-YL)-4-PROPOXY-3,6-DIHYDRO-2H-1,2-OXAZINE
Compound 1 4-SYN (3S,4'S)-3-(2',2'-DIMETHYL-1',3'-DIOXOLAN-4'-YL)-4-METHOXY-2-METHYL-3,6-DIHYDRO-2H-1,2-OXAZINE
Compound 8 (Z),(Z)-(2R,3R)-N,N'-(2,3-O-ISOPROPYLIDENE-2,3-DIHYDROXY-1,4-BUTYLIDENE)-BIS-(METHYLAMINE)-N,N'-DIOXIDE
Compound 9 -ANTI (3R,4'S)-2-BENZYL-3-(2',2'-DIMETHYL-1',3'-DIOXOLAN-4'-YL)-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE
Compound 9 -SYN (3S,4'S)-2-BENZYL-3-(2',2'-DIMETHYL-1',3'-DIOXOLAN-4'-YL)-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE
Compound 10-ANTI (3R,4'S)-2-BENZYL-4-BENZYLOXY-3-(2',2'-DIMETHYL-1',3'-DIOXOLAN-4'-YL)-3,6-DIHYDRO-2H-1,2-OXAZINE
Compound 10-SYN (3S,4'S)-2-BENZYL-4-BENZYLOXY-3-(2',2'-DIMETHYL-1',3'-DIOXOLAN-4'-YL)-3,6-DIHYDRO-2H-1,2-OXAZINE
Compound 12-SYN (3S,4'S)-2-BENZYL-3-(2',2'-DIMETHYL-1',3'-DIOXOLAN-4'-YL)-4-(3,3-DIMETHYLBUTOXY)-3,6-DIHYDRO-2H-1,2-OXAZINE
Compound 13-ANTI (3R,4'S)-2-BENZYL-3-(2',2'-DIMETHYL-1',3'-DIOXOLAN-4'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE
![(3R,4'S)-2-BENZYL-3-(2',2'-DIMETHYL-1',3'-DIOXOLAN-4'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE](/api/compound/KHYG5RszYsH.png?h=300&w=458 "(3R,4'S)-2-BENZYL-3-(2',2'-DIMETHYL-1',3'-DIOXOLAN-4'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE")
Compound 13-SYN (3S,4'S)-2-BENZYL-3-(2',2'-DIMETHYL-1',3'-DIOXOLAN-4'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE
![(3S,4'S)-2-BENZYL-3-(2',2'-DIMETHYL-1',3'-DIOXOLAN-4'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE](/api/compound/IXugUkOnY8N.png?h=300&w=458 "(3S,4'S)-2-BENZYL-3-(2',2'-DIMETHYL-1',3'-DIOXOLAN-4'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE")
Compound 15 (4S)-4-(2'-METHOXY-1',3'-BUTADIENYL)-2,2-DIMETHYL-1,3-DIOXOLANE
Compound 16-ANTI (3R,2'R,4'S,5'R)-2-BENZYL-3-(5'-TERT.-BUTYLDIMETHYLSILOXY-2'-METHYL-1',3'-DIOXAN-4'-YL)-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE
Compound 16-SYN (3S,2'R,4'S,5'R)-2-BENZYL-3-(5'-TERT.-BUTYLDIMETHYLSILOXY-2'-METHYL-1',3'-DIOXAN-4'-YL)-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE
Compound 17-ANTI (3R,2'R,4'S,5'R)-2-BENZYL-3-(5'-HYDROXY-2'-METHYL-1',3'-DIOXAN-4'-YL)-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE
Compound 17-SYN (3S,2'R,4'S,5'R)-2-BENZYL-3-(5'-HYDROXY-2'-METHYL-1',3'-DIOXAN-4'-YL)-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE
Compound 18A (4A-R,5A-R,8R,9A-S,9B-R)-1-BENZYL-4A-METHOXY-8-METHYL-3,4,4A,5A,6,8,9A,9B-OCTADIHYDRO-1H-[1,3]-DIOXINO-[4',5':4,5]-FURO-[3,2-C]-[1,2]-OXAZINE
![(4A-R,5A-R,8R,9A-S,9B-R)-1-BENZYL-4A-METHOXY-8-METHYL-3,4,4A,5A,6,8,9A,9B-OCTADIHYDRO-1H-[1,3]-DIOXINO-[4',5':4,5]-FURO-[3,2-C]-[1,2]-OXAZINE](/api/compound/IIAx1ovBuxJ.png?h=300&w=458 "(4A-R,5A-R,8R,9A-S,9B-R)-1-BENZYL-4A-METHOXY-8-METHYL-3,4,4A,5A,6,8,9A,9B-OCTADIHYDRO-1H-[1,3]-DIOXINO-[4',5':4,5]-FURO-[3,2-C]-[1,2]-OXAZINE")
Compound 18B (4A-S,5A-R,8R,9A-S,9B-S)-1-BENZYL-4A-METHOXY-8-METHYL-3,4,4A,5A,6,8,9A,9B-OCTADIHYDRO-1H-[1,3]-DIOXINO-[4',5':4,5]-FURO-[3,2-C]-[1,2]-OXAZINE
![(4A-S,5A-R,8R,9A-S,9B-S)-1-BENZYL-4A-METHOXY-8-METHYL-3,4,4A,5A,6,8,9A,9B-OCTADIHYDRO-1H-[1,3]-DIOXINO-[4',5':4,5]-FURO-[3,2-C]-[1,2]-OXAZINE](/api/compound/90WFo1mPhTz.png?h=300&w=458 "(4A-S,5A-R,8R,9A-S,9B-S)-1-BENZYL-4A-METHOXY-8-METHYL-3,4,4A,5A,6,8,9A,9B-OCTADIHYDRO-1H-[1,3]-DIOXINO-[4',5':4,5]-FURO-[3,2-C]-[1,2]-OXAZINE")
Compound 19-ANTI (3R,2'R,4'S,5'R)-3-(5'-HYDROXY-2'-METHYL-1',3'-DIOXAN-4'-YL)-4-METHOXY-2-METHYL-3,6-DIHYDRO-2H-1,2-OXAZINE
Compound 19-SYN (3S,2'R,4'S,5'R)-3-(5'-HYDROXY-2'-METHYL-1',3'-DIOXAN-4'-YL)-4-METHOXY-2-METHYL-3,6-DIHYDRO-2H-1,2-OXAZINE
Compound 20-ANTI (3S,2'S,4'R,5'R)-2-BENZYL-3-(5'-HYDROXY-2'-METHYL-1',3'-DIOXAN-4'-YL)-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE
Compound 20-SYN (3R,2'S,4'R,5'R)-2-BENZYL-3-(5'-HYDROXY-2'-METHYL-1',3'-DIOXAN-4'-YL)-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE
Compound 22 (3S,2'S,4'R,5'R)-2-BENZYL-3-(5'-TERT.-BUTYLDIMETHYLSILYLOXY-2'-METHYL-1',3'-DIOXAN-4'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE
![(3S,2'S,4'R,5'R)-2-BENZYL-3-(5'-TERT.-BUTYLDIMETHYLSILYLOXY-2'-METHYL-1',3'-DIOXAN-4'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE](/api/compound/5hJ7pGPPbZu.png?h=300&w=458 "(3S,2'S,4'R,5'R)-2-BENZYL-3-(5'-TERT.-BUTYLDIMETHYLSILYLOXY-2'-METHYL-1',3'-DIOXAN-4'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE")
Compound 22 (3R,2'S,4'R,5'R)-2-BENZYL-3-(5'-TERT.-BUTYLDIMETHYLSILYLOXY-2'-METHYL-1',3'-DIOXAN-4'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE
![(3R,2'S,4'R,5'R)-2-BENZYL-3-(5'-TERT.-BUTYLDIMETHYLSILYLOXY-2'-METHYL-1',3'-DIOXAN-4'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE](/api/compound/Cgh7gSMwLVA.png?h=300&w=458 "(3R,2'S,4'R,5'R)-2-BENZYL-3-(5'-TERT.-BUTYLDIMETHYLSILYLOXY-2'-METHYL-1',3'-DIOXAN-4'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE")
Compound 23-ANTI (3R,4'S,5'R,4''R)-2-BENZYL-3-(2',2',2'',2''-TETRAMETHYL-[4',4'']-BI-[1,3-DIOXOLANYL]-5'-YL)-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE
![(3R,4'S,5'R,4''R)-2-BENZYL-3-(2',2',2'',2''-TETRAMETHYL-[4',4'']-BI-[1,3-DIOXOLANYL]-5'-YL)-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE](/api/compound/A93BWnwY92n.png?h=300&w=458 "(3R,4'S,5'R,4''R)-2-BENZYL-3-(2',2',2'',2''-TETRAMETHYL-[4',4'']-BI-[1,3-DIOXOLANYL]-5'-YL)-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE")
Compound 23-SYN (3S,4'S,5'R,4''R)-2-BENZYL-3-(2',2',2'',2''-TETRAMETHYL-[4',4'']-BI-[1,3-DIOXOLANYL]-5'-YL)-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE
![(3S,4'S,5'R,4''R)-2-BENZYL-3-(2',2',2'',2''-TETRAMETHYL-[4',4'']-BI-[1,3-DIOXOLANYL]-5'-YL)-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE](/api/compound/ANJkAyDoWom.png?h=300&w=458 "(3S,4'S,5'R,4''R)-2-BENZYL-3-(2',2',2'',2''-TETRAMETHYL-[4',4'']-BI-[1,3-DIOXOLANYL]-5'-YL)-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE")
Compound 24- (3S,4'S,5'R,4''R)-2-BENZYL-3-(2',2',2'',2''-TETRAMETHYL-[4',4'']-BI-[1,3-DIOXOLANYL]-5'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE
![(3S,4'S,5'R,4''R)-2-BENZYL-3-(2',2',2'',2''-TETRAMETHYL-[4',4'']-BI-[1,3-DIOXOLANYL]-5'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE](/api/compound/2qKUEaE1acj.png?h=300&w=458 "(3S,4'S,5'R,4''R)-2-BENZYL-3-(2',2',2'',2''-TETRAMETHYL-[4',4'']-BI-[1,3-DIOXOLANYL]-5'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE")
Compound 24- (3R,4'S,5'R,4''R)-2-BENZYL-3-(2',2',2'',2''-TETRAMETHYL-[4',4'']-BI-[1,3-DIOXOLANYL]-5'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE
![(3R,4'S,5'R,4''R)-2-BENZYL-3-(2',2',2'',2''-TETRAMETHYL-[4',4'']-BI-[1,3-DIOXOLANYL]-5'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE](/api/compound/DHR54tQl79A.png?h=300&w=458 "(3R,4'S,5'R,4''R)-2-BENZYL-3-(2',2',2'',2''-TETRAMETHYL-[4',4'']-BI-[1,3-DIOXOLANYL]-5'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE")
Compound 27 (E,E)-(5R,6R)-5,6-ISOPROPYLIDENEDIOXY-3,8-DIMETHOXY-1,3,7,9-DECATETRAENE
Compound 28-ANTI (E)-(3S,4'R,5'R)-2-METHYL-3-[5'-(2-METHOXY-1,3-BUTADIENYL)-2',2'-DIMETHYL-1',3'-DIOXOLAN-4'-YL]-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE
![(E)-(3S,4'R,5'R)-2-METHYL-3-[5'-(2-METHOXY-1,3-BUTADIENYL)-2',2'-DIMETHYL-1',3'-DIOXOLAN-4'-YL]-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE](/api/compound/DXxTjtcv83V.png?h=300&w=458 "(E)-(3S,4'R,5'R)-2-METHYL-3-[5'-(2-METHOXY-1,3-BUTADIENYL)-2',2'-DIMETHYL-1',3'-DIOXOLAN-4'-YL]-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE")
Compound 28-SYN (E)-(3R,4'R,5'R)-2-METHYL-3-[5'-(2-METHOXY-1,3-BUTADIENYL)-2',2'-DIMETHYL-1',3'-DIOXOLAN-4'-YL]-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE
![(E)-(3R,4'R,5'R)-2-METHYL-3-[5'-(2-METHOXY-1,3-BUTADIENYL)-2',2'-DIMETHYL-1',3'-DIOXOLAN-4'-YL]-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE](/api/compound/9X3yq2nqWKv.png?h=300&w=458 "(E)-(3R,4'R,5'R)-2-METHYL-3-[5'-(2-METHOXY-1,3-BUTADIENYL)-2',2'-DIMETHYL-1',3'-DIOXOLAN-4'-YL]-4-METHOXY-3,6-DIHYDRO-2H-1,2-OXAZINE")
2-(TRIMETHYLSILYL)-ETHOXYALLENE
3,3-DIMETHYLBUTOXYALLENE
BENZYLOXYALLENE
Citation
| Citation | EUR.J.ORG.CHEM.,1003(2005) |
|---|---|
| Journal | European Journal of Organic Chemistry |
| Issue | 6 |
| Volume | 2005 |
| Page(s) | 1003-1019 |
| Year | 2005 |
| Author(s) | Matthias Helms, Wolfgang Schade, Robert Pulz, Toshiko Watanabe, Ahmed Al-Harrasi, Lubor Fišera, Iva Hlobilová, Gernot Zahn, Hans-Ulrich Reißig |
| Publisher | Wiley |
| DOI | 10.1002/ejoc.200400627 |