For citations & permissions, please see: Citations & Permissions - Wiley Science Solutions*

*Links on SpectraBase are not permalinks.

[(COD)-IR-(KAPPA(2)-L1)-PPH(3)];MAJOR-DIASTEREOMER

Compound with spectra: 2 NMR

[(COD)-IR-(KAPPA(2)-L1)-PPH(3)];MAJOR-DIASTEREOMER
SpectraBase Compound ID CVjWwFUEiwZ
InChI InChI=1S/C36H29NO2P.C18H15P.C8H8.Ir/c1-25(27-13-5-3-6-14-27)37(26(2)28-15-7-4-8-16-28)40-38-33-23-21-29-17-9-11-19-31(29)35(33)36-32-20-12-10-18-30(32)22-24-34(36)39-40;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-6-8-7-5-3-1;/h3-26H,1H2,2H3;1-15H;1-2,7-8H2;/q;;;-2/p+2/t25-,26-;;;/m0.../s1
InChIKey IWSTUUBTZBWLIU-RDZXZRSHSA-P
Mol Weight 1099.3 g/mol
Molecular Formula C62H54IrNO2P2
Exact Mass 1099.325903 g/mol
Parent InChIKey HDHOOLNMPZPDDQ-HWTGJJCHSA-P
Enantiomer InChIKey IWSTUUBTZBWLIU-YICTUOAMSA-P

View Spectrum of [(COD)-IR-(KAPPA(2)-L1)-PPH(3)];MAJOR-DIASTEREOMER

31P NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent THF-D8

View Spectrum of [(COD)-IR-(KAPPA(2)-L1)-PPH(3)];MAJOR-DIASTEREOMER

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent THF-D8
[(COD)-IR-(KAPPA(2)-L1)-PPH(3)];MINOR-DIASTEREOMER
Cobalt, bis(cyano-C)(2,7,18-triethyl-1,2,6,7,12,12,15,17-octamethyl-3,8,13,17-tetrapropyl-5(6H)-corrinonato-N21,N22,N23,N24)-, [OC-6-34-[1R-(1.alpha.,2.beta.,3.alpha.,6.alpha.,7.beta.,8.alpha.,13.alpha.,17.alpha.,18.beta.,19.beta.)]]-
13',16':18',21'-dietheno-1,1''-diethyl-3',14',20',31'-tetramethyldispiro[piperidine-4,17'-[5,12,22,29]tetraoxa[37,40,41]triazatetracyclo[31.13.1.0.(4,45).0(30,35)]heptatetraconta-1',3',13',15',18',20',30',34',35',45'-decaene-47',4''-piperidine]-38',42'-dione
(1R,5R,7S,8S,9S,10R)-1-[(2R*,5S)-5-[(2R,5R,6S)-5-benzyloxy-5-ethyl-6-methyltetrahydropyran-2-yl]-2-methoxy-5-methyltetrahydrofuran-2-yl]-9-ethyl-8,10-isopropylidenedioxy-1-(4-methoxybenzyloxy)-5,7-dimethyldodeca-2-yn-4-one
Iron, tricarbonyl[[2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-iodo-1-[(2,3,4,5-.eta.)-4-methoxy-1-methyl-2,4-cyclohexadien-1-yl]cyclopentyl]methyl benzoate]-, stereoisomer
6H,13H-5,13:6,12-Dietheno-5a,12a-(methaniminomethano)-1H,5H,8H,12H-[1,2,4]triazolo[1,2-a][1,2,4]triazolo[1',2':1,2]pyridazino[4,5-d]pyridazine-18-acetic acid, 2,3,9,10-tetrahydro-.alpha.-(2-methylpropyl)-1,3,8,10,17,19-hexaoxo-2,9-diphenyl-, hexyl ester, stereoisomer
Hexamethyl 7,9,30-trichloro-3,6,37,38-trimethoxy-1,13-diazapentacyclo[11.11.11.1(5,9).1(17,21),1(28,32)]octatriaconta-3,5,7,9(38),10,15,17,19,21(37),22,26,28,30,32(36),33-pentadecaene-3,11,15,23,26,34-hexacarboxylate
11-Cyano-4-hydroxy-5,17-dimethoxy-6,18,23-trimethyl-12,15,22-triazahexacyclo[10.9.0.1(2,9).0(3,8).1(13,16).0(20,21)]tricosa-3,5,7,13,16(21),17,19-hexaene-19-one
Dimethyl 2,anti-4,anti-9,12,anti-14-pentabromodecacyclo[9.9.0.0(1,8).0(2,12).0(6,10).0(11,18)0(13,17).0(16,20)] icosane-syn-4,syn-9-dicarboxylate
(3R,2'S,2''R)-3-(N-(tert-Butoxycarbonyl)pyrrolidine-2'-yl)-3-(2''-methoxy-2''-(trifluoromethyl)-2''-phenylacetyl)oxy)-1-(trimethylsilyl)prop-1-yne
(2S,5S,7S,9S,10S,12R,13R*,14R*)-9-[(1S,2R*)-1-Ethyl-2-hydroxybutyl]-2-[(2R,5R,6S)-5-ethyl-5-hydroxy-6-methyltetrahydropyran-2-yl]-15-(4-methoxybenzyloxy)-2,10,12-trimethyl-1,6,8-trioxodispiro[4.1.5.3]pentadecan-13,14-diol
Title Journal or Book Year
Identification of an Activated Catalyst in the Iridium-Catalyzed Allylic Amination and Etherification. Increased Rates, Scope, and Selectivity Journal of the American Chemical Society 2003
Other Resources
Unknown Identification

Search your unknown spectrum against the world's largest collection of reference spectra

KnowItAll Campus Solutions

KnowItAll offers faculty and students at your school access to all the tools you need for spectral analysis and structure drawing & publishing! Plus, access the world's largest spectral library.