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[(COD)-IR-(KAPPA(2)-L1)-PPH(3)];MINOR-DIASTEREOMER

Compound with spectra: 2 NMR

[(COD)-IR-(KAPPA(2)-L1)-PPH(3)];MINOR-DIASTEREOMER
SpectraBase Compound ID 5JU7WSlefWU
InChI InChI=1S/C36H29NO2P.C18H15P.C8H8.Ir/c1-25(27-13-5-3-6-14-27)37(26(2)28-15-7-4-8-16-28)40-38-33-23-21-29-17-9-11-19-31(29)35(33)36-32-20-12-10-18-30(32)22-24-34(36)39-40;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-6-8-7-5-3-1;/h3-26H,1H2,2H3;1-15H;1-2,7-8H2;/q;;;-2/p+2/t25-,26-;;;/m1.../s1
InChIKey IWSTUUBTZBWLIU-YICTUOAMSA-P
Mol Weight 1099.3 g/mol
Molecular Formula C62H54IrNO2P2
Exact Mass 1099.325903 g/mol
Parent InChIKey HDHOOLNMPZPDDQ-KUSCCAPHSA-P
Enantiomer InChIKey IWSTUUBTZBWLIU-RDZXZRSHSA-P

View Spectrum of [(COD)-IR-(KAPPA(2)-L1)-PPH(3)];MINOR-DIASTEREOMER

31P NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent THF-D8

View Spectrum of [(COD)-IR-(KAPPA(2)-L1)-PPH(3)];MINOR-DIASTEREOMER

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent THF-D8
[(COD)-IR-(KAPPA(2)-L1)-PPH(3)];MAJOR-DIASTEREOMER
22,25,30,33-Tetraoxa-1,19-diazapentacyclo[17.8.8.13,7.18,12.113,17]o ctatriaconta-3,5,7(38),8,10,12(37),13,15,17(36)-nonaene, 36,37,38-trimethoxy-5,10,15-trimethyl-
{(4a,5,6,7,7a-.eta.)-4-(2",2"-Dimethyl-1",3"-dioxolan-4"-yl)-3a,5,8,8a-tetrahydro-2,2-dimethyl-4H-indeno[5,6-d]-1,3-dioxol-5-yl}-{(4',5',6',7',7a'-.eta.)-5'-(chloromercurio)-4'-(2"',2"'-dimethyl-1'",3'"-dioxolan-4"'-yl}-3a',5',8',8a'-tetrahydro-2',2'-dimethyl-4H-indeno5,6-d]-1',3'-dioxol-5'-yl}- iron (II)
(3S*,6S*,7R*,8S*)-2,7-dimethyl-1,1-(1,2-ethylenedithio)-8-ethoxy-6-hydroxy-3-((2-mercaptoethyl)thio)bicyclo[5.3.0]dec-1-ene
21H-Biline-8-propanoic acid, 3-ethyl-1,17,18,19,22,24-hexahydro-17-(2-methoxy-2-oxoethyl)-2,7,12,13,18,18-hexamethyl-1,19-dioxo-, 9-anthracenylmethyl ester, (.+-.)-
Cobalt, bis(cyano-C)(2,7,18-triethyl-1,2,6,7,12,12,15,17-octamethyl-3,8,13,17-tetrapropyl-5(6H)-corrinonato-N21,N22,N23,N24)-, [OC-6-34-[1R-(1.alpha.,2.beta.,3.alpha.,6.alpha.,7.beta.,8.alpha.,13.alpha.,17.alpha.,18.beta.,19.beta.)]]-
21H,23H-Porphine-2,18-dipropanoic acid, (oxydiethylidene)bis[3,17,?,?-tetramethyl-, dimethyl ester, monoacetyl monoethenyl deriv.
6H,13H-5,13:6,12-Dietheno-5a,12a-(methaniminomethano)-1H,5H,8H,12H-[1,2,4]triazolo[1,2-a][1,2,4]triazolo[1',2':1,2]pyridazino[4,5-d]pyridazine-18-acetic acid, 2,3,9,10-tetrahydro-.alpha.-(2-methylpropyl)-1,3,8,10,17,19-hexaoxo-2,9-diphenyl-, hexyl ester, stereoisomer
13',16':18',21'-dietheno-1,1''-diethyl-3',14',20',31'-tetramethyldispiro[piperidine-4,17'-[5,12,22,29]tetraoxa[37,40,41]triazatetracyclo[31.13.1.0.(4,45).0(30,35)]heptatetraconta-1',3',13',15',18',20',30',34',35',45'-decaene-47',4''-piperidine]-38',42'-dione
Dispiro[piperidine-4,2'-[7,14,24,31]tetraoxapentacyclo[30.2.2.23,6.215,18.220,23]dotetraconta[3,5,15,17,20,22,32,34,35,37,39,41]dodecaen e-19',4''-piperidine], 1,1''-diacetyl-5',33'-dibromo-16',22',36',37',40',41'-hexamethyl-
Poly(Vinylacetate-co-vinylalcohol), (partially hydrolyzed polyvinylacetate), methanol solution
Title Journal or Book Year
Identification of an Activated Catalyst in the Iridium-Catalyzed Allylic Amination and Etherification. Increased Rates, Scope, and Selectivity Journal of the American Chemical Society 2003
Other Resources
Unknown Identification

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