(2S,4R)-1-[(E)-6-(TERT.-BUTYLDIPHENYLSILYLOXY)-2-METHYLHEX-2-ENYL]-2-(TERT.-BUTYLDIPHENYLSILYLOXYMETHYL)-4-(METHOXYMETHYLOXY)-PYRROLIDINE
Compound with spectra: 1 NMR
![(2S,4R)-1-[(E)-6-(TERT.-BUTYLDIPHENYLSILYLOXY)-2-METHYLHEX-2-ENYL]-2-(TERT.-BUTYLDIPHENYLSILYLOXYMETHYL)-4-(METHOXYMETHYLOXY)-PYRROLIDINE](/api/compound/CDxraVY0d7M.png?ph=true&h=300&w=458 "(2S,4R)-1-[(E)-6-(TERT.-BUTYLDIPHENYLSILYLOXY)-2-METHYLHEX-2-ENYL]-2-(TERT.-BUTYLDIPHENYLSILYLOXYMETHYL)-4-(METHOXYMETHYLOXY)-PYRROLIDINE")
| SpectraBase Compound ID | CDxraVY0d7M |
|---|---|
| InChI | InChI=1S/C46H63NO4Si2/c1-38(23-21-22-32-50-52(45(2,3)4,41-24-13-9-14-25-41)42-26-15-10-16-27-42)34-47-35-40(49-37-48-8)33-39(47)36-51-53(46(5,6)7,43-28-17-11-18-29-43)44-30-19-12-20-31-44/h9-20,23-31,39-40H,21-22,32-37H2,1-8H3/b38-23+/t39-,40-/m1/s1 |
| InChIKey | NQFBXJZHPKHIDB-GCUXPEDHSA-N |
| Mol Weight | 750.2 g/mol |
| Molecular Formula | C46H63NO4Si2 |
| Exact Mass | 749.429563 g/mol |
| Enantiomer InChIKey | NQFBXJZHPKHIDB-DYBSUOJPSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(2S,4R)-METHYL-1-[(E)-6-TERT.-BUTYLDIPHENYLSILYLOXY-2-METHYLHEX-2-ENYL]-4-(METHOXYMETHYLOXY)-PYRROLIDINE-2-CARBOXYLATE
(2S,3S)-2-[[tert-butyl(diphenyl)silyl]oxymethyl]-3-hydroxy-1-piperidinecarboxylic acid tert-butyl ester
(2S,8S)-8-[(2-BROMOACETYLAMINO)-METHYL]-2-(TERT.-BUTYLDIPHENYLSILANYLOXYMETHYL)-3,4,6,7,8,9-HEXAHYDRO-2H-PYRIMIDO-[1,2-A]-PYRIMIDIN-1-IUM
(2'S,5S)-2,2-Dimethyl-5-[3'-(diphenyl-t-butylsilyloxy)-2'-tosyloxypropyl]-1,3-dioxolane
(5S)-1-[3'-(tert-Butyldiphenylsilyl)propyl]-1,2,3-Trideoxy-4-O-methyl-.alpha.-D-glycero-pentopyranose-5-spiro-2"-tetrahydropyran
6-Methoxy-3-[3-(tert-butyldiphenylsilyloxy)propyl]-2,7-dioxaspiro[5.5]undecane
(2S,8S)-2-(TERT.-BUTYLDIPHENYLSILANYLOXYMETHYL)-8-METHANESULFONYLOXYMETHYL-3,4,6,7,8,9-HEXAHYDRO-2H-PYRIMIDO-[1,2-A]-PYRIMIDIN-1-IUM
ETHYL_2-METHYL-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-CYCLOHEX-2-EN-4-ONE_CARBOXYLATE
(2S,8S)-8-(TERT.-BUTYLDIPHENYLSILANYLOXYMETHYL)-2-(CARBOXYMETHYLSULFANYLMETHYL)-3,4,6,7,8,9-HEXAHYDRO-2H-PYRIMIDO-[1,2-A]-PYRIMIDIN-1-IUM
(2S,8S)-8-(2-BROMOACETOXYMETHYL)-2-(TERT.-BUTYLDIPHENYLSILANYLOXYMETHYL)-3,4,6,7,8,9-HEXAHYDRO-2H-PYRIMIDO-[1,2-A]-PYRIMIDIN-1-IUM
| Title | Journal or Book | Year |
|---|---|---|
| Zwitterionic Aza-Claisen Rearrangements Controlled by Pyrrolidine Auxiliaries - Useful Key Steps in Convergent Enantioselective Syntheses | European Journal of Organic Chemistry | 2012 |