(2S,4R)-METHYL-1-[(E)-6-TERT.-BUTYLDIPHENYLSILYLOXY-2-METHYLHEX-2-ENYL]-4-(METHOXYMETHYLOXY)-PYRROLIDINE-2-CARBOXYLATE
Compound with spectra: 1 NMR
![(2S,4R)-METHYL-1-[(E)-6-TERT.-BUTYLDIPHENYLSILYLOXY-2-METHYLHEX-2-ENYL]-4-(METHOXYMETHYLOXY)-PYRROLIDINE-2-CARBOXYLATE](/api/compound/3tpIwhU86yn.png?ph=true&h=300&w=458 "(2S,4R)-METHYL-1-[(E)-6-TERT.-BUTYLDIPHENYLSILYLOXY-2-METHYLHEX-2-ENYL]-4-(METHOXYMETHYLOXY)-PYRROLIDINE-2-CARBOXYLATE")
| SpectraBase Compound ID | 3tpIwhU86yn |
|---|---|
| InChI | InChI=1S/C31H45NO5Si/c1-25(22-32-23-26(36-24-34-5)21-29(32)30(33)35-6)15-13-14-20-37-38(31(2,3)4,27-16-9-7-10-17-27)28-18-11-8-12-19-28/h7-12,15-19,26,29H,13-14,20-24H2,1-6H3/b25-15+/t26-,29+/m1/s1 |
| InChIKey | LNZKQQHHUOBPIU-YDSUQFHQSA-N |
| Mol Weight | 539.8 g/mol |
| Molecular Formula | C31H45NO5Si |
| Exact Mass | 539.3067 g/mol |
| Enantiomer InChIKey | LNZKQQHHUOBPIU-MSOJPRELSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | C6D6 |
(2S,4R)-1-[(E)-6-(TERT.-BUTYLDIPHENYLSILYLOXY)-2-METHYLHEX-2-ENYL]-2-(TERT.-BUTYLDIPHENYLSILYLOXYMETHYL)-4-(METHOXYMETHYLOXY)-PYRROLIDINE
ETHYL_2-METHYL-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-CYCLOHEX-2-EN-4-ONE_CARBOXYLATE
TERT.-BUTYL-(2S,4R)-N-TERT.-BUTOXYCARBONYL-4-TERT.-BUTYLDIPHENYLSILYLOXYMETHYL-GLUTAMIC-ACID
2-DIPHENYLPHOSPHANYL-BENZOIC-ACID-8-(TERT.-BUTYLDIPHENYLSILANYLOXY)-OCTYLESTER
Methyl (2E,4S,5R,6R)-7-(tert-Butyldiphenylsilyloxy)-5-(3,4-dimethoxybenzyloxy)-4,6-dimethyl-2-heptenoate
(1S,2R,5S)-2-((R)-3-(tert-Butyldiphenylsiloxy)-1-hydroxypropyl)bicyclo[3.2.1]oct-6-en-3-one
(1R,2R,5R)-2-((R)-3-(tert-Butyldiphenylsiloxy)-1-hydroxypropyl)bicyclo[3.2.1]oct-6-en-3-one
(6R,7S)-6-benzoxy-7-[5-[tert-butyl(diphenyl)silyl]oxy-4-methyl-pentyl]-7-methyl-oxepan-3-one
(3S,4R,5S)-3-Acetoxy-5-(tert-butyldiphenylsiloxy)methyl-4-hydroxypyrrolidin-2-one
(2R,5S,6S)-6-tert-Butyldiphenylsilyloxymethyl-5,6-dihydro-2-methoxy-5-(4-methoxybenzyloxy)-2H-pyran
| Title | Journal or Book | Year |
|---|---|---|
| Zwitterionic Aza-Claisen Rearrangements Controlled by Pyrrolidine Auxiliaries - Useful Key Steps in Convergent Enantioselective Syntheses | European Journal of Organic Chemistry | 2012 |