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(CO)5CR=C(SCH2CH2OH)PH;((2-HYDROXYTHIOETHOXY)-PHENYLCARBENE)-PENTACARBONYL-COMPLEX-OF-CR
SpectraBase Compound ID BqkcMdgvfrq
InChI InChI=1S/C9H10OS.5CO.Cr/c10-6-7-11-8-9-4-2-1-3-5-9;5*1-2;/h1-5,10H,6-7H2;;;;;;
InChIKey DJQNONYZLAQZKM-UHFFFAOYSA-N
Mol Weight 358.28 g/mol
Molecular Formula C14H10CrO6S
Exact Mass 357.960314 g/mol
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
  • (CO)5CR=C(SCH2CH2OH)PH
Title Journal or Book Year
Physical Organic Chemistry of Transition Metal Carbene Complexes. 18.1 Kinetics of Reversible Cyclization of the Fischer Carbene Complexes (CO)5MC(SCH2CH2OH)Ph and (CO)5MC(OCH2CH2OH)Ph (M = Cr, W) in Aqueous Acetonitrile Journal of the American Chemical Society 2000
Physical Organic Chemistry of Transition Metal Carbene Complexes. 17.1 Kinetics of the Reactions of (Arylthioalkoxycarbene)pentacarbonyl Complexes of Chromium(0) and Tungsten(0) with Thiolate Ions in Aqueous Acetonitrile:  pKa Values of the Metal-Protonated Tetrahedral Adducts Formed between Carbene Complexes and Thiolate Ion Journal of the American Chemical Society 1999

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