John Wiley & Sons, Inc. SpectraBase; SpectraBase Compound ID=1pPHhzOa5x4

(accessed ).
(CO)5W=C(SCH2CH2OH)PH;((2-HYDROXYTHIOETHOXY)-PHENYLCARBENE)-PENTACARBONYL-COMPLEX-OF-WOLFRAM
SpectraBase Compound ID 1pPHhzOa5x4
InChI InChI=1S/C9H10OS.5CO.W/c10-6-7-11-8-9-4-2-1-3-5-9;5*1-2;/h1-5,10H,6-7H2;;;;;;
InChIKey VUXMEEGXPXJITO-UHFFFAOYSA-N
Mol Weight 490.13 g/mol
Molecular Formula C14H10O6SW
Exact Mass 489.970763 g/mol
Copyright Copyright © 2016-2021 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CD3CN
Copyright Copyright © 2016-2021 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
  • (CO)5W=C(SCH2CH2OH)PH
Title Journal or Book Year
Physical Organic Chemistry of Transition Metal Carbene Complexes. 18.1Kinetics of Reversible Cyclization of the Fischer Carbene Complexes (CO)5MC(SCH2CH2OH)Ph and (CO)5MC(OCH2CH2OH)Ph (M = Cr, W) in Aqueous Acetonitrile Journal of the American Chemical Society 2000
Physical Organic Chemistry of Transition Metal Carbene Complexes. 17.1Kinetics of the Reactions of (Arylthioalkoxycarbene)pentacarbonyl Complexes of Chromium(0) and Tungsten(0) with Thiolate Ions in Aqueous Acetonitrile:  pKaValues of the Metal-Protonated Tetrahedral Adducts Formed between Carbene Complexes and Thiolate Ion Journal of the American Chemical Society 1999
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