#18A;ANTI-(2S,3S)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S)-2-(METHOXYCARBONYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHYL]-4-METHYL-4-PENTENONE-1
Compound with spectra: 1 NMR
![#18A;ANTI-(2S,3S)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S)-2-(METHOXYCARBONYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHYL]-4-METHYL-4-PENTENONE-1](/api/compound/BQAtDCkdXTT.png?ph=true&h=300&w=458 "#18A;ANTI-(2S,3S)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S)-2-(METHOXYCARBONYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHYL]-4-METHYL-4-PENTENONE-1")
| SpectraBase Compound ID | BQAtDCkdXTT |
|---|---|
| InChI | InChI=1S/C40H53NO5Si/c1-30(2)35(23-16-28-46-47(40(3,4)5,33-19-10-8-11-20-33)34-21-12-9-13-22-34)36(26-25-31-17-14-18-32(29-31)44-6)38(42)41-27-15-24-37(41)39(43)45-7/h8-14,17-22,29,35-37H,1,15-16,23-28H2,2-7H3/t35-,36+,37+/m1/s1 |
| InChIKey | GHZZNVZFQRPUND-BOALQFNTSA-N |
| Mol Weight | 656.0 g/mol |
| Molecular Formula | C40H53NO5Si |
| Exact Mass | 655.3693 g/mol |
| Enantiomer InChIKey | GHZZNVZFQRPUND-HKIDPNTFSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
#17E;ANTI-(2R,3R)-1-[(2S)-2-(TERT.-BUTYLDIMETHYLSILYLOXYMETHYL)-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHYL]-4-ME
#17H;(2R,3R)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,4R)-4-METHOXY-2-(METHOXYMETHYL)-PYRROLIDIN-1-YL]-2-[2-(3-METHOXYPHENYL)-ETHYL]-4-METHYLPENT-4-EN-1-
#9A;ANTI-(2S,3S)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S)-2-(METHOXYCARBONYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-METHYL-4-PENTENONE-
#8A;ANTI-(2R,3R)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S)-2-(METHOXYCARBONYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-METHYL-4-PENTENONE-
#8E;ANTI-(2R,3R)-1-[(2S)-2-(TERT.-BUTYLDIMETHYLSILYLOXYMETHYL)-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-M
#10H;(2,3-SYN-1):(2R,3S)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,4R)-4-METHOXY-2-(METHOXYMETHYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-
#9H;MINOR-(2,3-ANTI):(2S,3S)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,4R)-4-METHOXY-2-(METHOXYMETHYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL
(2S,4S)-N-TERT.-BUTYLOXYCARBONYL-4-TERT.-BUTOXYDIPHENYLSILYLOXYMETHYLPYROGLUTAMATE
(2S,4R)-N-TERT.-BUTYLOXYCARBONYL-4-TERT.-BUTOXYDIPHENYLSILYLOXYMETHYLPYROGLUTAMATE
| Title | Journal or Book | Year |
|---|---|---|
| Zwitterionic Aza-Claisen Rearrangements Controlled by Pyrrolidine Auxiliaries - Useful Key Steps in Convergent Enantioselective Syntheses | European Journal of Organic Chemistry | 2012 |