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#8E;ANTI-(2R,3R)-1-[(2S)-2-(TERT.-BUTYLDIMETHYLSILYLOXYMETHYL)-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-M

Compound with spectra: 1 NMR

#8E;ANTI-(2R,3R)-1-[(2S)-2-(TERT.-BUTYLDIMETHYLSILYLOXYMETHYL)-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-M
SpectraBase Compound ID B0g9jc84WK1
InChI InChI=1S/C45H65NO4Si2/c1-35(2)41(28-20-32-49-52(45(6,7)8,39-24-14-12-15-25-39)40-26-16-13-17-27-40)42(30-29-36-21-18-23-38(33-36)48-9)43(47)46-31-19-22-37(46)34-50-51(10,11)44(3,4)5/h12-18,21,23-27,29-30,33,37,41-42H,1,19-20,22,28,31-32,34H2,2-11H3/b30-29+/t37-,41-,42+/m0/s1
InChIKey GNDVMGMAIKXBNY-METZKHHFSA-N
Mol Weight 740.2 g/mol
Molecular Formula C45H65NO4Si2
Exact Mass 739.445213 g/mol
Enantiomer InChIKey GNDVMGMAIKXBNY-BBZUQNQVSA-N

View Spectrum of #8E;ANTI-(2R,3R)-1-[(2S)-2-(TERT.-BUTYLDIMETHYLSILYLOXYMETHYL)-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-M

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
#17E;ANTI-(2R,3R)-1-[(2S)-2-(TERT.-BUTYLDIMETHYLSILYLOXYMETHYL)-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHYL]-4-ME
#16J;(2S,3S)-1-[(2S,4R)-4-TERT.-BUTOXY-2-METHOXYMETHYL-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-METHYL-3-[3-(4-NITROPHENYL)-CARBONYLOXYPROPYL]-4-
#18A;ANTI-(2S,3S)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S)-2-(METHOXYCARBONYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHYL]-4-METHYL-4-PENTENONE-1
#17H;(2R,3R)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,4R)-4-METHOXY-2-(METHOXYMETHYL)-PYRROLIDIN-1-YL]-2-[2-(3-METHOXYPHENYL)-ETHYL]-4-METHYLPENT-4-EN-1-
#SYN-21B;(4R)-3-[[2R,3S,(4Z)]-5-[[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY-METHYL]-3-HYDROXY-9-METHYL-2-(3-METHYL-BUT-3-ENYL)-DECA-4,8-DIENOYL]-4-ISOPROPYL-1,3-OXAZO
#ANTI-21B;(4R)-3-[[2S,3S,(4Z)]-5-[[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY-METHYL]-3-HYDROXY-9-METHYL-2-(3-METHYL-BUT-3-ENYL)-DECA-4,8-DIENOYL]-4-ISOPROPYL-1,3-OXAZ
(Z)-1-[Benzyl-2-[(t-butyldiphenylsilyl)oxymethyl]-4-[(isopropenylpyrrolidinyl)ethenyl] Diisopropylcarbamate
(Z)-2-[(2S,3S,4R)-1-BENZYL-2-([[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-METHYL)-4-ISOPROPENYLPYRROLIDINYL]-ETHENYL-DIISOPROPYLCARBAMATE
(Z)-2-[(2S,3R,4S)-1-BENZYL-2-([[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-METHYL)-4-ISOPROPENYLPYRROLIDINYL]-ETHENYL-DIISOPROPYLCARBAMATE
2-[2'-(t-Butyldiphenylsilyl)oxyethyl]-3-methyl-1,6,8-trioxa-dispiro[4.1.5.2]tetradec-1-ene
Title Journal or Book Year
Zwitterionic Aza-Claisen Rearrangements Controlled by Pyrrolidine Auxiliaries - Useful Key Steps in Convergent Enantioselective Syntheses European Journal of Organic Chemistry 2012
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