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(2S,4R)-1-[(E)-6-(TERT.-BUTYLDIPHENYLSILYLOXY)-2-METHYLHEX-2-ENYL]-4-TERT.-BUTOXY-2-(TERT.-BUTOXYMETHYL)-PYRROLIDINE

Compound with spectra: 1 NMR

(2S,4R)-1-[(E)-6-(TERT.-BUTYLDIPHENYLSILYLOXY)-2-METHYLHEX-2-ENYL]-4-TERT.-BUTOXY-2-(TERT.-BUTOXYMETHYL)-PYRROLIDINE
SpectraBase Compound ID 8qMzjTnEMqq
InChI InChI=1S/C36H57NO3Si/c1-29(26-37-27-31(40-35(5,6)7)25-30(37)28-38-34(2,3)4)19-17-18-24-39-41(36(8,9)10,32-20-13-11-14-21-32)33-22-15-12-16-23-33/h11-16,19-23,30-31H,17-18,24-28H2,1-10H3/b29-19+/t30-,31+/m0/s1
InChIKey HLCJMJFCMWHLSJ-NJDDHJSSSA-N
Mol Weight 579.9 g/mol
Molecular Formula C36H57NO3Si
Exact Mass 579.410771 g/mol
Enantiomer InChIKey HLCJMJFCMWHLSJ-KABIVQQVSA-N

View Spectrum of (2S,4R)-1-[(E)-6-(TERT.-BUTYLDIPHENYLSILYLOXY)-2-METHYLHEX-2-ENYL]-4-TERT.-BUTOXY-2-(TERT.-BUTOXYMETHYL)-PYRROLIDINE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
RJBIWSAVZGAIBV-YSEONISGSA-N
(2S,4R)-1-[(E)-6-(TERT.-BUTYLDIPHENYLSILYLOXY)-2-METHYLHEX-2-ENYL]-4-(METHOXYMETHYLOXY)-2-(METHOXYMETHOXYMETHYL)-PYRROLIDINE
(2S,4R)-METHYL-1-[(E)-6-TERT.-BUTYLDIPHENYLSILYLOXY-2-METHYLHEX-2-ENYL]-4-HYDROXYPYRROLIDINE-2-CARBOXYLATE
Methyl 2-{1'-(3"-t-butyldiphenylsilyloxy)propyl]vinyl}-5-oxocyclopentanecarboxylate
TERT.-BUTYL-(2S,4S)-4-TERT.-BUTYLDIPHENYLSILYLOXYMETHYL-PYROGLUTAMATE
[(2R,3S,6R)-6-[3-[tert-butyl(diphenyl)silyl]oxypropyl]-3-hydroxy-tetrahydropyran-2-yl]methyl 4-methylbenzenesulfonate
(2S,3R,4aS,8aR)-2-[2-[tert-butyl(diphenyl)silyl]oxyethyl]-2,3,4,4a,6,7,8,8a-octahydropyrano[3,2-b]pyran-3-ol
(2S,3S,4aR,8aR)-2-[2-[tert-butyl(diphenyl)silyl]oxyethyl]-2,3,4,4a,6,7,8,8a-octahydropyrano[3,2-b]pyran-3-ol
(2R,3S)-2-[(1-Benzyloxy)cyclopropyl]-3-({[tert-butyl(diphenyl)silyl]oxy}methyl)aziridine
(4R*,5R*)-2,2,5-Trimethyl-4-[4-(tert-butyldiphenylsilyloxy)butyl]-4-methoxymethyl-1,3-dioxolane
Title Journal or Book Year
Zwitterionic Aza-Claisen Rearrangements Controlled by Pyrrolidine Auxiliaries - Useful Key Steps in Convergent Enantioselective Syntheses European Journal of Organic Chemistry 2012
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