(2S,4R)-1-[(E)-6-(TERT.-BUTYLDIPHENYLSILYLOXY)-2-METHYLHEX-2-ENYL]-4-(METHOXYMETHYLOXY)-2-(METHOXYMETHOXYMETHYL)-PYRROLIDINE
Compound with spectra: 1 NMR
![(2S,4R)-1-[(E)-6-(TERT.-BUTYLDIPHENYLSILYLOXY)-2-METHYLHEX-2-ENYL]-4-(METHOXYMETHYLOXY)-2-(METHOXYMETHOXYMETHYL)-PYRROLIDINE](/api/compound/Avp1cGwB4Ps.png?ph=true&h=300&w=458 "(2S,4R)-1-[(E)-6-(TERT.-BUTYLDIPHENYLSILYLOXY)-2-METHYLHEX-2-ENYL]-4-(METHOXYMETHYLOXY)-2-(METHOXYMETHOXYMETHYL)-PYRROLIDINE")
| SpectraBase Compound ID | Avp1cGwB4Ps |
|---|---|
| InChI | InChI=1S/C32H49NO5Si/c1-27(22-33-23-29(37-26-35-6)21-28(33)24-36-25-34-5)15-13-14-20-38-39(32(2,3)4,30-16-9-7-10-17-30)31-18-11-8-12-19-31/h7-12,15-19,28-29H,13-14,20-26H2,1-6H3/b27-15+/t28-,29+/m0/s1 |
| InChIKey | HVYZNLFTIKYMFJ-LGOBFTGNSA-N |
| Mol Weight | 555.8 g/mol |
| Molecular Formula | C32H49NO5Si |
| Exact Mass | 555.338 g/mol |
| Enantiomer InChIKey | HVYZNLFTIKYMFJ-OHYGIWOOSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
RJBIWSAVZGAIBV-YSEONISGSA-N
(2S,4R)-METHYL-1-[(E)-6-TERT.-BUTYLDIPHENYLSILYLOXY-2-METHYLHEX-2-ENYL]-4-HYDROXYPYRROLIDINE-2-CARBOXYLATE
Methyl 2-{1'-(3"-t-butyldiphenylsilyloxy)propyl]vinyl}-5-oxocyclopentanecarboxylate
(2S,9R,10S)-9-(5-(TERT.-BUTYLDIPHENYLSILYLOXY)-PENTYL)-2-(HYDROXYMETHYL)-1-OXAQUINOLIZIDINE;HYDROCHLORIDE-SALT
(2S)-2-(tert-Butyldiphenylsilyloxymethyl)-1-azabicyclo[2.2.2]octan-5-ol
(2R)-2-(tert-Butyldiphenylsilyloxymethyl)-1-azabicyclo[2.2.2]octan-5-ol
13-tert-Butyldiphenylsilyloxy-2-diphenylphosphinoyltridecan-3-one
7-tert-Butyldiphenylsilyloxy-2-diphenylphosphinoylheptan-3-one
8-tert-Butyldiphenylsilyloxy-2-diphenylphosphinoyloctan-3-one
(2S)-2-(tert-Butyldiphenylsilyloxymethyl)-1-azabicyclo[2.2.2]octan-5-one
| Title | Journal or Book | Year |
|---|---|---|
| Zwitterionic Aza-Claisen Rearrangements Controlled by Pyrrolidine Auxiliaries - Useful Key Steps in Convergent Enantioselective Syntheses | European Journal of Organic Chemistry | 2012 |