(-)-(S)-N,N-DIMETHYLAMINO-S-[(Z)-(3R,4R)-3-ISOPROPYL-4-(4-BROMOPHENYL)-4-[(TRIETHYLSILYL)-OXY]-BUT-ENYL]-PHENYL-SULFOXONIUM-TETRAFLUOROBORATE
Compound with spectra: 1 NMR
![(-)-(S)-N,N-DIMETHYLAMINO-S-[(Z)-(3R,4R)-3-ISOPROPYL-4-(4-BROMOPHENYL)-4-[(TRIETHYLSILYL)-OXY]-BUT-ENYL]-PHENYL-SULFOXONIUM-TETRAFLUOROBORATE](/api/compound/3wInL335iQq.png?ph=true&h=300&w=458 "(-)-(S)-N,N-DIMETHYLAMINO-S-[(Z)-(3R,4R)-3-ISOPROPYL-4-(4-BROMOPHENYL)-4-[(TRIETHYLSILYL)-OXY]-BUT-ENYL]-PHENYL-SULFOXONIUM-TETRAFLUOROBORATE")
| SpectraBase Compound ID | 3wInL335iQq |
|---|---|
| InChI | InChI=1S/C27H41BrNO2SSi.BF4/c1-8-33(9-2,10-3)31-27(23-16-18-24(28)19-17-23)26(22(4)5)20-21-32(30,29(6)7)25-14-12-11-13-15-25;2-1(3,4)5/h11-22,26-27H,8-10H2,1-7H3;/q+1;-1/b21-20-;/t26-,27-,32?;/m0./s1 |
| InChIKey | UQNORYPLVVXZMZ-FGZKACQBSA-N |
| Mol Weight | 638.5 g/mol |
| Molecular Formula | C27H41BBrF4NO2SSi |
| Exact Mass | 637.183983 g/mol |
| Parent InChIKey | AYTOJUCOLOPFDW-DFTQLLJLSA-N |
| Enantiomer InChIKey | UQNORYPLVVXZMZ-WFPWUJBHSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(-)-TRIETHYL-[(Z)-(1R,2R)-2-ISOPROPYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-METHOXPHENYL)-BUT-3-ENYLOXY]-SILANE
(Z)-{(t-Butyl)-[2-isopropyl-1-phenyl-4-[(S)-(N-methyl-(S)-phenylsulfon)imidoyl]but-3-enyloxy}dimethylsilane
(-)-TRIETHYL-[(Z)-(1R,2R)-2-CYCLOHEXYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-PHENYLETHYNYL-BUT-3-ENYLOXY]-SILANE
(-)-(4R,5R)-TRIETHYL-[4-ISOPROPYL-3-METHYL-5-(4-BROMOPHENYL)-4,5-DIHYDRO-FURAN-2-YL]-SILANE
Allyl (5S,6S,7R,8R)-5-azido-6-methyl-7-hydroxy-8-[(tert-butyldimethylsilyl)oxy]-8-phenyloct-2(E)-enoate
2-(4-fluorophenyl)-3-methyl-2-trimethylsilyloxy-cyclopropane-1-carboxylic acid methyl ester
3-(1',1'-Dimethylethyl)-4-ethyl-2-phenyl-3-[(trimethylsilyl)oxy]oxetane
Fexofenadine 2TMS
tert-Butyl-dimethyl-[[(1S,4S,5S)-2-(phenylthio)-5-bicyclo[2.2.2]oct-2-enyl]oxy]silane
Fexofenadine -H2O 2TMS
| Title | Journal or Book | Year |
|---|---|---|
| Asymmetric Synthesis of anti-Homopropargylic Alcohols from Aldehydes and Chiral Sulfonimidoyl Substituted Bis(allyl)titanium Complexes through Generation and Elimination of Novel Chiral Alkylidenecarbene (Dimethylamino)sulfoxonium Ylides | Journal of the American Chemical Society | 2002 |