(-)-TRIETHYL-[(Z)-(1R,2R)-2-CYCLOHEXYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-PHENYLETHYNYL-BUT-3-ENYLOXY]-SILANE
Compound with spectra: 1 NMR
![(-)-TRIETHYL-[(Z)-(1R,2R)-2-CYCLOHEXYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-PHENYLETHYNYL-BUT-3-ENYLOXY]-SILANE](/api/compound/72ZGtRBsKYt.png?ph=true&h=300&w=458 "(-)-TRIETHYL-[(Z)-(1R,2R)-2-CYCLOHEXYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-PHENYLETHYNYL-BUT-3-ENYLOXY]-SILANE")
| SpectraBase Compound ID | 72ZGtRBsKYt |
|---|---|
| InChI | InChI=1S/C31H43NO2SSi/c1-5-36(6-2,7-3)34-31(24-23-27-17-11-8-12-18-27)30(28-19-13-9-14-20-28)25-26-35(33,32-4)29-21-15-10-16-22-29/h8,10-12,15-18,21-22,25-26,28,30-31H,5-7,9,13-14,19-20H2,1-4H3/b26-25-/t30-,31+,35?/m1/s1 |
| InChIKey | AFXPBGLPECVQTO-TUSHTDQUSA-N |
| Mol Weight | 521.8 g/mol |
| Molecular Formula | C31H43NO2SSi |
| Exact Mass | 521.278377 g/mol |
| Enantiomer InChIKey | AFXPBGLPECVQTO-KHAFXVNBSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(+)-(E,S(S),2S,3R)-5-(N-METHYL-S-PHENYLSULFONIMIDOYL)-3-ISOPROPYL-2-(2-METHYLPROPANE-2-SULFONYLAMINO)-PENT-4-ENOIC-ACID-ETHYLESTER
(-)-(S)-N,N-DIMETHYLAMINO-S-[(Z)-(3R,4R)-3-ISOPROPYL-4-(4-BROMOPHENYL)-4-[(TRIETHYLSILYL)-OXY]-BUT-ENYL]-PHENYL-SULFOXONIUM-TETRAFLUOROBORATE
(1R,2S,4aR,8S,8aS)-2-methyl-8-tri(propan-2-yl)silyloxy-1,2,4a,5,6,7,8,8a-octahydronaphthalene-1-carbaldehyde
1-Formyl-8-(triisopropylsilyl)oxy-2-methyl-1.beta.,2.alpha.,(4a).alpha.,5,6,7,8.beta.,(8a).beta.-octahydronaphthalene
tert-Butyl-dimethyl-[[(1S,4S,5S)-2-(phenylthio)-5-bicyclo[2.2.2]oct-2-enyl]oxy]silane
S-Phenyl-S-(2-cyclohexyl)hexyl-N-(toluene-p-sulfonyl)sulfoximine
S-Phenyl-S-[(E)-1-Methyl-4-phenylbut-1-enyl]-N-(p-tolylsulfonyl)sulfoxime
(2E)-2-[(2S,3S,6R)-2-[tert-butyl(dimethyl)silyl]oxy-3-isopropyl-6-methyl-cyclohexylidene]acetic acid ethyl ester
3-[(1S,2S,4aR,8S,8aS)-2-methyl-8-tri(propan-2-yl)silyloxy-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]-1-propanol
(1R)-1-[(1R)-2-(benzenesulfonyl)-2-ethenylcyclopropyl]-5-[tert-butyl(dimethyl)silyl]oxy-1-pentanol
| Title | Journal or Book | Year |
|---|---|---|
| Asymmetric Synthesis of anti-Homopropargylic Alcohols from Aldehydes and Chiral Sulfonimidoyl Substituted Bis(allyl)titanium Complexes through Generation and Elimination of Novel Chiral Alkylidenecarbene (Dimethylamino)sulfoxonium Ylides | Journal of the American Chemical Society | 2002 |