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E-4-[(4S)-4-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-OXO-4,5-DIHYDROFURAN-3-YLIDENE]-2,2-DIMETHYLBUTANAL

Compound with spectra: 1 NMR

E-4-[(4S)-4-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-OXO-4,5-DIHYDROFURAN-3-YLIDENE]-2,2-DIMETHYLBUTANAL
SpectraBase Compound ID 3QkQpdT1zHX
InChI InChI=1S/C26H32O4Si/c1-25(2,3)31(20-12-8-6-9-13-20,21-14-10-7-11-15-21)30-23-18-29-24(28)22(23)16-17-26(4,5)19-27/h6-16,19,23H,17-18H2,1-5H3/b22-16+/t23-/m1/s1
InChIKey UXLYHETVMVUBJH-PLJYQOKSSA-N
Mol Weight 436.6 g/mol
Molecular Formula C26H32O4Si
Exact Mass 436.206986 g/mol
Enantiomer InChIKey UXLYHETVMVUBJH-GTRUEHEQSA-N
Racemate InChIKey UXLYHETVMVUBJH-CJLVFECKSA-N

View Spectrum of E-4-[(4S)-4-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-OXO-4,5-DIHYDROFURAN-3-YLIDENE]-2,2-DIMETHYLBUTANAL

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
(1E,3E,7E,11E)-13-teryt-Butyldiphenylsiloxy-1-isopropyl-4,8,12-trimethylcyclotetradeca-1,3,7,11-tetraene
Ethyl 5-[(t-butyldiphenylsilyl)oxy]-4-methyl-3-cyclohexene-1-carboxylate
Ethyl (1S,5S)-5-[(t-butyldiphenylsilyl)oxy]-4-methyl-3-cyclohex-3-ene-1-carboxylate
Methyl (1S,5S)-5-[(t-butyldiphenylsilyl)oxy]-4-methyl-3-cyclohex-3-ene-1-carboxylate
5-[tert-butyl(diphenyl)silyl]oxy-4-methyl-1-cyclohex-3-enecarboxylic acid methyl ester
(3R,5R)-6,10-Dimethyl-3-isopropenyl-14-oxo-5-(tert-butyldiphenylsiloxy)-(6E,10E)-pentadecadien-1-al
1-O-Benzyl-2-O-(t-butyldiphenylsilyl)-3,4-O-isopropylidenebutane-1,2,3,4-tetrol
(5S)-5-[tert-butyl(diphenyl)silyl]oxy-5-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-pentynoic acid ethyl ester
(2S,3S)-2-bromo-3-[tert-butyl(diphenyl)silyl]oxy-succinic acid diethyl ester
[[(1R,2Z/2E,4S)-1-[(1S)-2-(benzyloxy)-1-methylethyl]-4-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-pentenyl]-oxy]-tert-butyldihenylsilane
Title Journal or Book Year
The Remarkable Effect of Cosolvent on a Samarium(II)-Mediated 4-exo-trig Cyclization:  Further Synthetic Studies on Pestalotiopsin A The Journal of Organic Chemistry 2003
E-4-[(4S)-4-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-OXO-4,5-DIHYDROFURAN-3-YLIDENE]-2,2-DIMETHYLBUTANAL
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