| SpectraBase Spectrum ID |
Lk8NcsOZK9c |
| Name |
(2R,4S,6R)-6-[tert-butyl(dimethyl)silyl]oxy-4-methyl-heptan-2-ol |
| Appearance |
Colorless oil |
| Copyright |
Copyright © 2020-2024 John Wiley & Sons, Inc. All Rights Reserved. |
| Exact Mass |
260.217156803 u |
| Formula |
C14H32O2Si |
| InChI |
InChI=1S/C14H32O2Si/c1-11(9-12(2)15)10-13(3)16-17(7,8)14(4,5)6/h11-13,15H,9-10H2,1-8H3/t11-,12+,13+/m0/s1 |
| InChIKey |
VAYMAMZYDGTMJO-YNEHKIRRSA-N |
| Instrument Name |
Finnigan MAT 95Q or Finnigan MAT 90 or JEOL JMS-700 |
| Ionization Type |
EI |
| Literature Reference DOI |
10.1002/anie.201800792 |
| Molecular Weight |
260.493 g/mol |
| Optical Rotation |
[a]D20 = -16.0 (c = 0.40, CDCl3) |
| Quality |
86 |
| Reported Formula |
C14H32O2Si |
| SMILES |
O[C@@](C[C@@](C[C@](O[Si](C(C)(C)C)(C)C)(C)[H])(C)[H])(C)[H] |
| SPLASH |
splash10-014i-9500000000-4dd6954fba3301ffdea2 |
| Sample Comments |
dr = 99:1, >99% ee |
| Source of Spectrum |
ACI-57-SM59-2R,4S,6R-17 (DOI: 10.1002/anie.201800792) |
| Wiley ID |
1890723 |
![(2R,4S,6R)-6-[tert-butyl(dimethyl)silyl]oxy-4-methyl-heptan-2-ol](/api/spectrum/Lk8NcsOZK9c/structure.png?h=300&w=458 "(2R,4S,6R)-6-[tert-butyl(dimethyl)silyl]oxy-4-methyl-heptan-2-ol")
