| SpectraBase Spectrum ID |
L2IoavcNDQ6 |
| Name |
(4R,5R)-4-[(3,4-dichlorophenyl)methyl]-2,2,5-trimethyl-5-(trifluoromethyl)oxasilolane |
| Appearance |
Yellowish oil |
| Copyright |
Copyright © 2020-2024 John Wiley & Sons, Inc. All Rights Reserved. |
| Exact Mass |
356.037781590 u |
| Formula |
C14H17Cl2F3OSi |
| InChI |
InChI=1S/C14H17Cl2F3OSi/c1-13(14(17,18)19)10(8-21(2,3)20-13)6-9-4-5-11(15)12(16)7-9/h4-5,7,10H,6,8H2,1-3H3/t10-,13+/m0/s1 |
| InChIKey |
IDTHNMBIJNEWLE-GXFFZTMASA-N |
| Instrument Name |
GCMS |
| Ionization Type |
EI |
| Literature Reference DOI |
10.1002/anie.202208861 |
| Molecular Weight |
357.275 g/mol |
| Optical Rotation |
[a]D20 = -12.0 (c = 0.50, CHCl3) |
| Quality |
275 |
| Reported Formula |
C14H17OF3Si(35)Cl2 |
| SMILES |
C1(=C(C=C(C=C1)C[C@]1(C[Si](O[C@@]1(C)C(F)(F)F)(C)C)[H])Cl)Cl |
| SPLASH |
splash10-00fr-8902000000-567d4cece23f4b4b874f |
| Sample Comments |
dr = 13:1, 91% ee |
| Source of Spectrum |
ACI-61-SM10-5h (DOI: 10.1002/anie.202208861) |
| Wiley ID |
1899468 |
![(4R,5R)-4-[(3,4-dichlorophenyl)methyl]-2,2,5-trimethyl-5-(trifluoromethyl)oxasilolane](/api/spectrum/L2IoavcNDQ6/structure.png?h=300&w=458 "(4R,5R)-4-[(3,4-dichlorophenyl)methyl]-2,2,5-trimethyl-5-(trifluoromethyl)oxasilolane")
