| SpectraBase Spectrum ID |
BX6gaEFMRsQ |
| Name |
tert-Butyl 2-(3-((2R*,3S*)-3-(1-(triethylsiloxy)vinyl)oxiran-2-yl)propyl)-1H-pyrrole-1-carboxylate |
| Appearance |
Pale yellow oil |
| Copyright |
Copyright © 2020-2024 John Wiley & Sons, Inc. All Rights Reserved. |
| Exact Mass |
407.249185206 u |
| Formula |
C22H37NO4Si |
| InChI |
InChI=1S/C22H37NO4Si/c1-8-28(9-2,10-3)27-17(4)20-19(25-20)15-11-13-18-14-12-16-23(18)21(24)26-22(5,6)7/h12,14,16,19-20H,4,8-11,13,15H2,1-3,5-7H3/t19-,20-/m1/s1 |
| InChIKey |
MZYORRJMOSNHSD-WOJBJXKFSA-N |
| Ionization Type |
EI |
| Literature Reference DOI |
10.1002/anie.201711439 |
| Molecular Weight |
407.626 g/mol |
| Optical Rotation |
[a]D21.1 = +13.5 (c = 3.48, DCM) |
| Quality |
47 |
| Reported Formula |
C22H37NO4Si |
| SMILES |
C([C@@]1([C@](O1)(CCCC1=CC=CN1C(OC(C)(C)C)=O)[H])[H])(O[Si](CC)(CC)CC)=C |
| SPLASH |
splash10-00dr-0962000000-060182e653f2cf7b0d32 |
| Sample Comments |
94% ee |
| Source of Spectrum |
ACI-57-SM25-2a (DOI: 10.1002/anie.201711439) |
| Thin-Layer Chromatography |
0.53 (EtOAc/hexane, 5%) |
| Wiley ID |
1890661 |
