| SpectraBase Spectrum ID |
9lN6VYwzWWH |
| Name |
(2R,4R)-2-([1,1'-biphenyl]-4-yl)-2-(bromomethyl)-4-methyl-4-phenylcyclopentan-1-one |
| Appearance |
Amorphous white solid |
| Copyright |
Copyright © 2020-2024 John Wiley & Sons, Inc. All Rights Reserved. |
| Formula |
C25H23BrO |
| InChI |
InChI=1S/C25H23BrO/c1-24(21-10-6-3-7-11-21)16-23(27)25(17-24,18-26)22-14-12-20(13-15-22)19-8-4-2-5-9-19/h2-15H,16-18H2,1H3/t24-,25+/m0/s1 |
| InChIKey |
UYGCYYURPOPVAZ-LOSJGSFVSA-N |
| Instrument Name |
Agilent 7890A-5975C GC |
| Ionization Type |
EI |
| Literature Reference DOI |
10.1021/acs.joc.1c02699 |
| Molecular Weight |
419.362 g/mol |
| Optical Rotation |
[a]D20 = +44.9 (c = 1, CHCl3) |
| Reported Formula |
C25H23OBr |
| SMILES |
C1[C@@](CC([C@]1(CBr)c1ccc(cc1)-c1ccccc1)=O)(C)c1ccccc1 |
| SPLASH |
splash10-004i-0900000000-4e6fb89056b79d0cc148 |
| Sample Comments |
92% ee, dr >20:1 |
| Source of Spectrum |
JOC-87-SM31-3g |
| Thin-Layer Chromatography |
Rf = 0.37 (PE/EtAcO, 95:5) |
| Wiley ID |
1884218 |
![(2R,4R)-2-([1,1'-biphenyl]-4-yl)-2-(bromomethyl)-4-methyl-4-phenylcyclopentan-1-one](/api/spectrum/9lN6VYwzWWH/structure.png?h=300&w=458 "(2R,4R)-2-([1,1'-biphenyl]-4-yl)-2-(bromomethyl)-4-methyl-4-phenylcyclopentan-1-one")
