| SpectraBase Spectrum ID |
88WDMt94uhh |
| Name |
(5S,6R)-Methyl 5,6-bis((tert-butyldimethylsilyl)oxy)oct-7-enoate |
| Appearance |
Colorless oil |
| Carrier Gas |
Hydrogen (30 ml/min) |
| Copyright |
Copyright © 2020-2024 John Wiley & Sons, Inc. All Rights Reserved. |
| Exact Mass |
416.277812963 u |
| Formula |
C21H44O4Si2 |
| GC Column |
Macherey-Nagel-1-MS (30 m x 0.25 mm) |
| GC Oven Program |
Oven temp 300oC |
| InChI |
InChI=1S/C21H44O4Si2/c1-13-17(24-26(9,10)20(2,3)4)18(15-14-16-19(22)23-8)25-27(11,12)21(5,6)7/h13,17-18H,1,14-16H2,2-12H3/t17-,18+/m1/s1 |
| InChIKey |
QYBXZOVETTYPRB-MSOLQXFVSA-N |
| Instrument Name |
Agilent HP6890-5937N |
| Ionization Type |
EI |
| Literature Reference DOI |
10.1002/ejoc.202201424 |
| Molecular Weight |
416.749 g/mol |
| Optical Rotation |
[a]D20 = -11.4 (436 nm), -6.19 (546 nm), -5.59 (579 nm), -5.59 (589 nm) (c = 0.50, CHCl3) |
| Quality |
206 |
| SMILES |
C([C@]([C@@](O[Si](C(C)(C)C)(C)C)(CCCC(OC)=O)[H])(O[Si](C(C)(C)C)(C)C)[H])=C |
| SPLASH |
splash10-006w-9520000000-896e1d2d46010d9a6ef4 |
| Source of Spectrum |
K1-26-SM24-18 (DOI: 10.1002/ejoc.202201424) |
| Thin-Layer Chromatography |
0.74 (CyHex/EtOAc, 5:1) |
| Wiley ID |
1910577 |
