| SpectraBase Spectrum ID |
78G1n6d1zNM |
| Name |
(1R,7aS)-1-((Triethylsilyl)oxy)-2-((S)-4-(trimethylsilyl)but-3-yn-2-yl)tetrahydro-1H-pyrrolo[1,2-c]imidazol-3(2H)-one |
| Appearance |
Pale yellow oil |
| Copyright |
Copyright © 2020-2024 John Wiley & Sons, Inc. All Rights Reserved. |
| Formula |
C19H36N2O2Si2 |
| InChI |
InChI=1S/C19H36N2O2Si2/c1-8-25(9-2,10-3)23-18-17-12-11-14-20(17)19(22)21(18)16(4)13-15-24(5,6)7/h16-18H,8-12,14H2,1-7H3/t16-,17-,18+/m0/s1 |
| InChIKey |
UMGKZQHRFJYPEQ-OKZBNKHCSA-N |
| Instrument Name |
Micromass GCT |
| Ionization Type |
EI |
| Literature Reference DOI |
10.1002/adsc.202000574 |
| Molecular Weight |
380.679 g/mol |
| Optical Rotation |
[a]D = -58.5 (c = 1.02, acetone) |
| Reported Formula |
C19H36N2O2Si2 |
| SMILES |
C1(=O)N([C@](C#C[Si](C)(C)C)(C)[H])[C@](O[Si](CC)(CC)CC)([C@]2([H])CCCN12)[H] |
| SPLASH |
splash10-00fs-6914000000-6f702750a91af6f6250b |
| Sample Comments |
dr > 95:5 |
| Source of Spectrum |
ASC-362-4402-11b |
| Thin-Layer Chromatography |
Rf = 0.32 (silica gel, EtOAc/hexanes, 20:80) |
| Wiley ID |
1855554 |
![(1R,7aS)-1-((Triethylsilyl)oxy)-2-((S)-4-(trimethylsilyl)but-3-yn-2-yl)tetrahydro-1H-pyrrolo[1,2-c]imidazol-3(2H)-one](/api/spectrum/78G1n6d1zNM/structure.png?h=300&w=458 "(1R,7aS)-1-((Triethylsilyl)oxy)-2-((S)-4-(trimethylsilyl)but-3-yn-2-yl)tetrahydro-1H-pyrrolo[1,2-c]imidazol-3(2H)-one")
