| SpectraBase Spectrum ID |
6e7PvniO25X |
| Name |
(5R,8S,9S,10S,13E,15S)-8-(tert-Butyldimethylsilanyloxy)-[(1R)-1,2-dimethylallyl]-9,10-epoxy-5-methyl-6,12-dimethylene-4-oxacyclopentadec-13-ene-2,4-dione |
| Appearance |
Colorless oil |
| Copyright |
Copyright © 2020-2024 John Wiley & Sons, Inc. All Rights Reserved. |
| Exact Mass |
488.295801047 u |
| Formula |
C28H44O5Si |
| InChI |
InChI=1S/C28H44O5Si/c1-17(2)20(5)23-13-12-18(3)14-24-27(32-24)25(33-34(10,11)28(7,8)9)15-19(4)21(6)22(29)16-26(30)31-23/h12-13,20-21,23-25,27H,1,3-4,14-16H2,2,5-11H3/b13-12+/t20-,21-,23+,24+,25+,27+/m1/s1 |
| InChIKey |
ZEFHBWPPAHMQAO-TWDZONSWSA-N |
| Ionization Type |
EI |
| Literature Reference DOI |
10.1021/jo4002382 |
| Molecular Weight |
488.740 g/mol |
| Optical Rotation |
[a]D23 = -42.0 (c = 0.27, CHCl3) |
| Quality |
94 |
| Reported Formula |
C28H44O5Si |
| SMILES |
[C@]12(CC(\C=C\[C@](OC(CC([C@@](C(C[C@@]([C@]2(O1)[H])(O[Si](C)(C)C(C)(C)C)[H])=C)(C)[H])=O)=O)([C@](C)(C(=C)C)[H])[H])=C)[H] |
| SPLASH |
splash10-001r-2693500000-cd493bf4133e76386d8f |
| Source of Spectrum |
JOC-78-4776-55 (DOI: 10.1021/jo4002382) |
| Thin-Layer Chromatography |
0.41 (EtOAc/hexanes, 15%) |
| Wiley ID |
1912124 |
![(5R,8S,9S,10S,13E,15S)-8-(tert-Butyldimethylsilanyloxy)-[(1R)-1,2-dimethylallyl]-9,10-epoxy-5-methyl-6,12-dimethylene-4-oxacyclopentadec-13-ene-2,4-dione](/api/spectrum/6e7PvniO25X/structure.png?h=300&w=458 "(5R,8S,9S,10S,13E,15S)-8-(tert-Butyldimethylsilanyloxy)-[(1R)-1,2-dimethylallyl]-9,10-epoxy-5-methyl-6,12-dimethylene-4-oxacyclopentadec-13-ene-2,4-dione")
