| SpectraBase Spectrum ID |
61GfGIUalmi |
| Name |
ethyl (2R,5S)-5-[tert-butyl(diphenyl)silyl]oxy-2-methyl-hexanoate |
| Appearance |
Colorless oil |
| Copyright |
Copyright © 2020-2024 John Wiley & Sons, Inc. All Rights Reserved. |
| Exact Mass |
412.243371551 u |
| Formula |
C25H36O3Si |
| InChI |
InChI=1S/C25H36O3Si/c1-7-27-24(26)20(2)18-19-21(3)28-29(25(4,5)6,22-14-10-8-11-15-22)23-16-12-9-13-17-23/h8-17,20-21H,7,18-19H2,1-6H3/t20-,21+/m1/s1 |
| InChIKey |
CKQYAIBWCXOHJX-RTWAWAEBSA-N |
| Instrument Name |
Finnigan MAT 95Q or Finnigan MAT 90 or JEOL JMS-700 |
| Ionization Type |
EI |
| Literature Reference DOI |
10.1002/anie.201800792 |
| Molecular Weight |
412.645 g/mol |
| Optical Rotation |
[a]D23 = -45.9 (c = 0.15, CHCl3) |
| Quality |
188 |
| Reported Formula |
C25H36O3Si |
| SMILES |
[C@@](CC[C@](C(OCC)=O)(C)[H])(O[Si](C(C)(C)C)(C1=CC=CC=C1)C1=CC=CC=C1)(C)[H] |
| SPLASH |
splash10-0a4i-0519000000-5fbb765cffac10494be9 |
| Sample Comments |
dr = 99:1, 99% ee |
| Source of Spectrum |
ACI-57-SM44-2R,5S-9h (DOI: 10.1002/anie.201800792) |
| Wiley ID |
1890726 |
![ethyl (2R,5S)-5-[tert-butyl(diphenyl)silyl]oxy-2-methyl-hexanoate](/api/spectrum/61GfGIUalmi/structure.png?h=300&w=458 "ethyl (2R,5S)-5-[tert-butyl(diphenyl)silyl]oxy-2-methyl-hexanoate")
