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Methyl (E)-4-((2S,4R,6R)-4-((tert-butyldimethylsilyl)oxy)-6-((S)-2-methyl-3-oxopropyl)tetrahydro-2H-pyran-2-yl)but-2-enoate

View entire compound with spectra: 2 MS (GC)

Methyl (E)-4-((2S,4R,6R)-4-((tert-butyldimethylsilyl)oxy)-6-((S)-2-methyl-3-oxopropyl)tetrahydro-2H-pyran-2-yl)but-2-enoate
SpectraBase Compound ID 7YIzk9iiSyj
InChI InChI=1S/C20H36O5Si/c1-15(14-21)11-17-13-18(25-26(6,7)20(2,3)4)12-16(24-17)9-8-10-19(22)23-5/h8,10,14-18H,9,11-13H2,1-7H3/b10-8+/t15-,16-,17+,18+/m0/s1
InChIKey BUHNSQDWMQKKGM-JGSNSIEISA-N
Mol Weight 384.6 g/mol
Molecular Formula C20H36O5Si
Exact Mass 384.233201 g/mol

Mass Spectrum (GC)

Mass Spectrum (GC)

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SpectraBase Spectrum ID 5EyIsUotq8P
Name Methyl (E)-4-((2S,4R,6R)-4-((tert-butyldimethylsilyl)oxy)-6-((S)-2-methyl-3-oxopropyl)tetrahydro-2H-pyran-2-yl)but-2-enoate
Appearance Colorless oil
Copyright Copyright © 2020-2024 John Wiley & Sons, Inc. All Rights Reserved.
Exact Mass 384.233200789 u
Formula C20H36O5Si
InChI InChI=1S/C20H36O5Si/c1-15(14-21)11-17-13-18(25-26(6,7)20(2,3)4)12-16(24-17)9-8-10-19(22)23-5/h8,10,14-18H,9,11-13H2,1-7H3/b10-8+/t15-,16-,17+,18+/m0/s1
InChIKey BUHNSQDWMQKKGM-JGSNSIEISA-N
Instrument Name Finnigan MAT 8200
Ionization Type EI
Literature Reference DOI 10.1002/chem.201501491
Molecular Weight 384.588 g/mol
Optical Rotation [a]D20 = +17.7 (c = 1.105, CH2Cl2)
Quality 448
Reported Formula C20H36O5Si
SMILES C(\C=C\C(OC)=O)[C@@]1(O[C@@](C[C@@](C1)(O[Si](C(C)(C)C)(C)C)[H])(C[C@](C)(C=O)[H])[H])[H]
SPLASH splash10-004i-9632000000-cc5a5a975cc2f6fbb9c5
Source of Spectrum QE-21-SM26-11-epi-15 (DOI: 10.1002/chem.201501491)
Wiley ID 1906723