| SpectraBase Spectrum ID |
3w8YceN1RbJ |
| Name |
(1R,7aS)-2-((4S)-4-(biphenyl-4-yl)-4-hydroxy-3-(trimethylsilyl)buta-1,2-dienyl)-1-(triethylsilyloxy)tetrahydro-1H-pyrrolo[1,2-c]imidazol-3(2H)-one |
| Appearance |
Viscous colorless oil |
| Copyright |
Copyright © 2020-2024 John Wiley & Sons, Inc. All Rights Reserved. |
| Formula |
C31H44N2O3Si2 |
| InChI |
InChI=1S/C31H44N2O3Si2/c1-7-38(8-2,9-3)36-30-27-16-13-22-32(27)31(35)33(30)23-21-28(37(4,5)6)29(34)26-19-17-25(18-20-26)24-14-11-10-12-15-24/h10-12,14-15,17-20,23,27,29-30,34H,7-9,13,16,22H2,1-6H3/t21?,27-,29-,30+/m0/s1 |
| InChIKey |
OIXHRVCPWYEPRN-ADUMFITESA-N |
| Instrument Name |
Micromass GCT |
| Ionization Type |
EI |
| Literature Reference DOI |
10.1002/adsc.202000574 |
| Molecular Weight |
548.874 g/mol |
| Optical Rotation |
[a]D = +128.5 (c = 1.05, acetone) |
| Reported Formula |
C31H44N2O3Si2 |
| SMILES |
O[C@](C(=C=CN1[C@@]([C@]2(N(C1=O)CCC2)[H])(O[Si](CC)(CC)CC)[H])[Si](C)(C)C)(c1ccc(cc1)-c1ccccc1)[H] |
| SPLASH |
splash10-015c-1997220000-c4c4ec1d68aad13c4bb9 |
| Source of Spectrum |
ASC-362-4408-epi-19h |
| Thin-Layer Chromatography |
Rf = 0.54 (silica gel, EtOAc/hexanes, 30:70) |
| Wiley ID |
1855578 |
![(1R,7aS)-2-((4S)-4-(biphenyl-4-yl)-4-hydroxy-3-(trimethylsilyl)buta-1,2-dienyl)-1-(triethylsilyloxy)tetrahydro-1H-pyrrolo[1,2-c]imidazol-3(2H)-one](/api/spectrum/3w8YceN1RbJ/structure.png?h=300&w=458 "(1R,7aS)-2-((4S)-4-(biphenyl-4-yl)-4-hydroxy-3-(trimethylsilyl)buta-1,2-dienyl)-1-(triethylsilyloxy)tetrahydro-1H-pyrrolo[1,2-c]imidazol-3(2H)-one")
