| SpectraBase Spectrum ID |
3DWAKQFzU5p |
| Name |
(4R,5R)-4-[(3-chlorophenyl)methyl]-2,2,5-trimethyl-5-(trifluoromethyl)oxasilolane |
| Appearance |
Yellowish oil |
| Copyright |
Copyright © 2020-2025 John Wiley & Sons, Inc. All Rights Reserved. |
| Exact Mass |
322.076753923 u |
| Formula |
C14H18ClF3OSi |
| InChI |
InChI=1S/C14H18ClF3OSi/c1-13(14(16,17)18)11(9-20(2,3)19-13)7-10-5-4-6-12(15)8-10/h4-6,8,11H,7,9H2,1-3H3/t11-,13+/m0/s1 |
| InChIKey |
CIFWZCMDUMHRHB-WCQYABFASA-N |
| Instrument Name |
GCMS |
| Ionization Type |
EI |
| Literature Reference DOI |
10.1002/anie.202208861 |
| Molecular Weight |
322.830 g/mol |
| Optical Rotation |
[a]D20 = -11.0 (c = 0.70, CHCl3) |
| Quality |
238 |
| Reported Formula |
C14H18OF3Si(35)Cl |
| SMILES |
C1=C(C=C(C=C1)C[C@]1(C[Si](O[C@@]1(C)C(F)(F)F)(C)C)[H])Cl |
| SPLASH |
splash10-00fr-5901000000-30c7860f5c63e05c0922 |
| Sample Comments |
dr = 11:1, 95% ee |
| Source of Spectrum |
ACI-61-SM10-5f (DOI: 10.1002/anie.202208861) |
| Wiley ID |
1899466 |
![(4R,5R)-4-[(3-chlorophenyl)methyl]-2,2,5-trimethyl-5-(trifluoromethyl)oxasilolane](/api/spectrum/3DWAKQFzU5p/structure.png?h=300&w=458 "(4R,5R)-4-[(3-chlorophenyl)methyl]-2,2,5-trimethyl-5-(trifluoromethyl)oxasilolane")
