| SpectraBase Spectrum ID |
2o2lP0qsrlA |
| Name |
4-((Tert-butyldimethylsilyl)oxy)-4-methyloctan-2-one |
| Carrier Gas |
Hydrogen (30 ml/min, 1.2 bar) |
| Copyright |
Copyright © 2020-2024 John Wiley & Sons, Inc. All Rights Reserved. |
| Exact Mass |
272.217156803 u |
| Formula |
C15H32O2Si |
| GC Column |
Optima-1-MS (30 m x 0.25 mm) |
| GC Oven Program |
Oven temp 300oC |
| InChI |
InChI=1S/C15H32O2Si/c1-9-10-11-15(6,12-13(2)16)17-18(7,8)14(3,4)5/h9-12H2,1-8H3 |
| InChIKey |
QHAIGQHTCOYFRD-UHFFFAOYSA-N |
| Instrument Name |
Agilent HP6890-5937 N |
| Ionization Type |
EI |
| Literature Reference DOI |
10.1002/chem.202004843 |
| Molecular Weight |
272.504 g/mol |
| Optical Rotation |
[a]D20 = 23.79 (589nm) (c = 0.325/100ml, CH3Cl) |
| Quality |
174 |
| SMILES |
C(CCC(CC(C)=O)(C)O[Si](C(C)(C)C)(C)C)C |
| SPLASH |
splash10-0ar0-9510000000-060b5ea1ea25d2a69c43 |
| Sample Comments |
85% ee |
| Source of Spectrum |
QE-27-SM51-30 (DOI: 10.1002/chem.202004843) |
| Thin-Layer Chromatography |
0.63 (SiO2, cHex/EtOAc, 10:1) |
| Wiley ID |
1902008 |
