| SpectraBase Spectrum ID |
1aBctt60VU |
| Name |
(2R,4R)-1,1-Dicyclopropyl-2-methyl-4-((triisopropylsilyl)oxy)pentan-1-ol |
| Appearance |
Colorless oil |
| Copyright |
Copyright © 2020-2024 John Wiley & Sons, Inc. All Rights Reserved. |
| Exact Mass |
354.295407125 u |
| Formula |
C21H42O2Si |
| InChI |
InChI=1S/C21H42O2Si/c1-14(2)24(15(3)4,16(5)6)23-18(8)13-17(7)21(22,19-9-10-19)20-11-12-20/h14-20,22H,9-13H2,1-8H3/t17-,18-/m1/s1 |
| InChIKey |
MSTDQVGLUFYDTF-QZTJIDSGSA-N |
| Ionization Type |
EI |
| Literature Reference DOI |
10.1002/anie.202116625 |
| Molecular Weight |
354.650 g/mol |
| Optical Rotation |
[a]D20 = -12.5 (c = 0.17, CHCl3) |
| Quality |
66 |
| Reported Formula |
C21H42O2Si |
| SMILES |
OC([C@@](C[C@@](C)(O[Si](C(C)C)(C(C)C)C(C)C)[H])(C)[H])(C1CC1)C1CC1 |
| SPLASH |
splash10-03e9-0900000000-05288c958ab88282f2f9 |
| Sample Comments |
dr = 99:1, 98% ee |
| Source of Spectrum |
ACI-61-SM32-9a (DOI: 10.1002/anie.202116625) |
| Wiley ID |
1897534 |
