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tert-butyl-dimethyl-[(2R,3R)-2,3,6,10-tetramethyldodeca-5,9-dienoxy]silane
SpectraBase Compound ID JhfHOaEMNrH
InChI InChI=1S/C22H44OSi/c1-11-18(2)13-12-14-19(3)15-16-20(4)21(5)17-23-24(9,10)22(6,7)8/h13,15,20-21H,11-12,14,16-17H2,1-10H3/t20-,21+/m1/s1
InChIKey DXUQGXNBJSWCRP-RTWAWAEBSA-N
Mol Weight 352.7 g/mol
Molecular Formula C22H44OSi
Exact Mass 352.316143 g/mol

Mass Spectrum (GC)

Mass Spectrum (GC)

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SpectraBase Spectrum ID 15MAISt5eOH
Name tert-butyl-dimethyl-[(2R,3R)-2,3,6,10-tetramethyldodeca-5,9-dienoxy]silane
Appearance Colorless oil
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Formula C22H44OSi
InChI InChI=1S/C22H44OSi/c1-11-18(2)13-12-14-19(3)15-16-20(4)21(5)17-23-24(9,10)22(6,7)8/h13,15,20-21H,11-12,14,16-17H2,1-10H3/t20-,21+/m1/s1
InChIKey DXUQGXNBJSWCRP-RTWAWAEBSA-N
Instrument Name FINNIGAN MAT 95Q
Ionization Type EI
Literature Reference DOI 10.1002/anie.201811330
Molecular Weight 352.678 g/mol
Optical Rotation [a]D20 = -1.2 (c = 2.0, CHCl3)
Reported Formula C22H44OSi
SMILES CC(CC)=CCCC(C)=CC[C@]([C@@](C)(CO[Si](C(C)(C)C)(C)C)[H])(C)[H]
SPLASH splash10-0032-9100000000-6d9934edd465c8b7d26a
Sample Comments dr = 97:3, 99% ee, 99% ee
Source of Spectrum ACI-58-SM48-2R,3R-28
Wiley ID 1840550