| SpectraBase Spectrum ID |
1031VbCdjT6 |
| Name |
ethyl (2S)-7-[tert-butyl(diphenyl)silyl]oxy-2-methyl-heptanoate |
| Appearance |
Colorless oil |
| Copyright |
Copyright © 2020-2024 John Wiley & Sons, Inc. All Rights Reserved. |
| Exact Mass |
426.259021616 u |
| Formula |
C26H38O3Si |
| InChI |
InChI=1S/C26H38O3Si/c1-6-28-25(27)22(2)16-10-9-15-21-29-30(26(3,4)5,23-17-11-7-12-18-23)24-19-13-8-14-20-24/h7-8,11-14,17-20,22H,6,9-10,15-16,21H2,1-5H3/t22-/m0/s1 |
| InChIKey |
JDFHONBDFIRCCA-QFIPXVFZSA-N |
| Instrument Name |
Finnigan MAT 95Q or Finnigan MAT 90 or JEOL JMS-700 |
| Ionization Type |
EI |
| Literature Reference DOI |
10.1002/anie.201800792 |
| Molecular Weight |
426.672 g/mol |
| Optical Rotation |
[a]D23 = 4.9 (c = 0.12, CHCl3) |
| Quality |
107 |
| Reported Formula |
C26H38O3Si |
| SMILES |
C(CCCC[C@@](C(OCC)=O)(C)[H])O[Si](C(C)(C)C)(C1=CC=CC=C1)C1=CC=CC=C1 |
| SPLASH |
splash10-014i-0529000000-829b609bb2c386e2f123 |
| Sample Comments |
93.8% ee |
| Source of Spectrum |
ACI-57-SM41-S-9f (DOI: 10.1002/anie.201800792) |
| Wiley ID |
1890753 |
![ethyl (2S)-7-[tert-butyl(diphenyl)silyl]oxy-2-methyl-heptanoate](/api/spectrum/1031VbCdjT6/structure.png?h=300&w=458 "ethyl (2S)-7-[tert-butyl(diphenyl)silyl]oxy-2-methyl-heptanoate")
