ANTI-(4RS,5SR)-(E)-5-DIPHENYLPHOSPHINOYLDEC-2-EN-4-OL
Compound with spectra: 1 NMR
| SpectraBase Compound ID | LMoFvVlwRQY |
|---|---|
| InChI | InChI=1S/C22H29O2P/c1-3-5-8-18-22(21(23)13-4-2)25(24,19-14-9-6-10-15-19)20-16-11-7-12-17-20/h4,6-7,9-17,21-23H,3,5,8,18H2,1-2H3/b13-4+/t21-,22-/m0/s1 |
| InChIKey | WICOFRMUUOKPOT-HYUVVOJVSA-N |
| Mol Weight | 356.45 g/mol |
| Molecular Formula | C22H29O2P |
| Exact Mass | 356.190517 g/mol |
| Enantiomer InChIKey | WICOFRMUUOKPOT-UOQMTPOMSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(trans-2-Hydroxycyclooctyl)diphenylphosphine oxide
(5RS,6SR)-6-Diphenylphosphinoyldecane-2,5-diol
(3RS,4SR,5RS)-4-DIPHENYLPHOSPHINOYL-HEPT-1-EN-3,5-DIOL;anti-SYN-ISOMER
(3RS,4RS,5SR)-4-DIPHENYLPHOSPHINOYL-HEPT-1-EN-3,5-DIOL;anti-anti-ISOMER
(3RS,4RS,5RS)-4-DIPHENYLPHOSPHINOYL-HEPT-1-EN-3,5-DIOL;SYN-anti-ISOMER
anti,anti-4-Diphenylphosphinoylhept-1-ene-3,5-diol
(2E,6E)-4-diphenylphosphorylocta-2,6-diene-1,5-diol
(3RS,5RS)-4-DIPHENYLPHOSPHINOYL-2,6-DIMETHYLHEPTA-1,6-DIEN-3,5-DIOL;SYN-anti-ISOMER
(3RS,4SR,5SR)-and(3RS,5RS)-4-Diphenylphosphinoyl-2,6-dimethylhepta-1,6-diene-3,5-diol
| Title | Journal or Book | Year |
|---|---|---|
| Stereochemical control (E/Z and syn/anti) by the diphenylphosphinoyl group in the synthesis of allylic alcohols by allylic rearrangement and by 1,4-diastereoselective reduction of enones | Journal of the Chemical Society, Perkin Transactions 1 | 1993 |
This compound is available in the following databases:
KnowItAll NMR Spectral Library
Author: Wiley
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