(3AS,4R,5R,6AR)-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-4-METHYLHEXAHYDROPENTALEN-2(1H)-ONE
Compound with spectra: 1 NMR
![(3AS,4R,5R,6AR)-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-4-METHYLHEXAHYDROPENTALEN-2(1H)-ONE](/api/compound/LKJMLJBD3fi.png?ph=true&h=300&w=458 "(3AS,4R,5R,6AR)-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-4-METHYLHEXAHYDROPENTALEN-2(1H)-ONE")
| SpectraBase Compound ID | LKJMLJBD3fi |
|---|---|
| InChI | InChI=1S/C25H32O2Si/c1-18-23-17-20(26)15-19(23)16-24(18)27-28(25(2,3)4,21-11-7-5-8-12-21)22-13-9-6-10-14-22/h5-14,18-19,23-24H,15-17H2,1-4H3/t18-,19+,23-,24-/m1/s1 |
| InChIKey | GLBRTXBHVKADRJ-RKGYPADOSA-N |
| Mol Weight | 392.6 g/mol |
| Molecular Formula | C25H32O2Si |
| Exact Mass | 392.217157 g/mol |
| Enantiomer InChIKey | GLBRTXBHVKADRJ-PLWWPAAYSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
Ethyl (1R,3S,4R)-5-[(t-butyldiphenylsilyl)oxy]-4-methyl-3-hydroxycyclohexane-1-carboxylate
Ethyl (1S,3S,4S)-3-[(t-butyldiphenylsilyl)oxy]-5-hydroxy-4-methylcyclohexane-1-carboxylate
(1R,3R,4R,5R)-3-(tert-Butyl-diphenyl-silanyloxy)-5-hydroxy-4-methyl-cyclohexanecarboxylic acid ethyl ester
Ethyl (1R,3R,4S)-5-[(t-butyldiphenylsilyl)oxy]-4-methyl-3-hydroxycyclohexane-1-carboxylate
Ethyl (1S,3S,4R)-3-[(t-butyldiphenylsilyl)oxy]-5-hydroxy-4-methylcyclohexane-1-carboxylate
Methyl (1S,3S,4R)-3-[(t-butyldiphenylsilyl)oxy]-5-hydroxy-4-methylcyclohexane-1-carboxylate
(1R,3R,4R,5R)-3-[tert-butyl(diphenyl)silyl]oxy-5-hydroxy-4-methyl-1-cyclohexanecarboxylic acid methyl ester
Methyl (1S,3S,4S)-3-[(t-butyldiphenylsilyl)oxy]-5-hydroxy-4-methylcyclohexane-1-carboxylate
Methyl (1R,3S,4R)-5-[(t-butyldiphenylsilyl)oxy]-4-methyl-3-hydroxycyclohexane-1-carboxylate
Methyl (1R,3R,4S)-5-[(t-butyldiphenylsilyl)oxy]-4-methyl-3-hydroxycyclohexane-1-carboxylate
| Title | Journal or Book | Year |
|---|---|---|
| Doing it Twice: Asymmetric Deprotonation/Alkylation of Weiss Diketone Derivatives as Key Steps in the Functionalization of Bicyclo[3.3.0]octanes | European Journal of Organic Chemistry | 2012 |