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3,4-BIS-O-(DIPHENYLPHOSPHINO)-1,6-DI-O-(TERT.-BUTYLDIPHENYLSILYL)-2,5-ANHYDRO-L-IDITOL

Compound with spectra: 2 NMR

3,4-BIS-O-(DIPHENYLPHOSPHINO)-1,6-DI-O-(TERT.-BUTYLDIPHENYLSILYL)-2,5-ANHYDRO-L-IDITOL
SpectraBase Compound ID LHC25rctq88
InChI InChI=1S/C62H66O5P2Si2/c1-61(2,3)70(53-39-23-11-24-40-53,54-41-25-12-26-42-54)63-47-57-59(66-68(49-31-15-7-16-32-49)50-33-17-8-18-34-50)60(67-69(51-35-19-9-20-36-51)52-37-21-10-22-38-52)58(65-57)48-64-71(62(4,5)6,55-43-27-13-28-44-55)56-45-29-14-30-46-56/h7-46,57-60H,47-48H2,1-6H3/t57-,58-,59+,60+/m0/s1
InChIKey LIPVTJDGVRBDRD-YFEQDRJUSA-N
Mol Weight 1009.3 g/mol
Molecular Formula C62H66O5P2Si2
Exact Mass 1008.392402 g/mol
Enantiomer InChIKey LIPVTJDGVRBDRD-GFNONAECSA-N

View Spectrum of 3,4-BIS-O-(DIPHENYLPHOSPHINO)-1,6-DI-O-(TERT.-BUTYLDIPHENYLSILYL)-2,5-ANHYDRO-L-IDITOL

31P NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3

View Spectrum of 3,4-BIS-O-(DIPHENYLPHOSPHINO)-1,6-DI-O-(TERT.-BUTYLDIPHENYLSILYL)-2,5-ANHYDRO-L-IDITOL

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
3,4-BIS-O-(DIPHENYLPHOSPHINO)-1,6-DI-O-(TERT.-BUTYLDIPHENYLSILYL)-2,5-ANHYDRO-D-MANNITOL
(((3aS,4R,6aS)-6-Bromo-2,2-dimethyl-tetrahydrofuro[3,4-d]-[1,3]dioxol-4-yl)methoxy)(tert-butyl)diphenylsilane
Methyl 6-O-(t-butyldiphenylsilyl)-4,5-O-isopropylidene-L-idonate
Methyl 6-O-(t-butyldiphenylsilyl)-4,5-O-isopropylidene-L-talonate
Methyl 6-O-(t-butyldiphenylsilyl)-4,5-O-isopropylidene-L-mannonate
Methyl 6-O-(t-butyldiphenylsilyl)-4,5-O-isopropylidene-L-galactonate
Methyl 6-O-(t-butyldiphenylsilyl)-4,5-O-isopropylidene-L-altronate
Methyl 6-O-(t-butyldiphenylsilyl)-4,5-O-isopropylidene-L-gulonate
METHYL-6-O-(TERT.-BUTYLDIPHENYLSILYL)-4-DEOXY-2,3-DI-O-METHYL-4-METHYLENE-ALPHA-D-XYLOHEXOPYRANOSIDE
1,7-Di-O-tert-butyl-diphenyl-silyl-2,3:5,6-di-O-isopropylidene-D-glycero-D-talo-heptitol
Title Journal or Book Year
C2-Symmetric Diphosphinite Ligands Derived from Carbohydrates. The Strong Influence of Remote Stereocenters on Asymmetric Rhodium-Catalyzed Hydrogenation The Journal of Organic Chemistry 2004

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