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#26;(+/-)-9-(1E,3Z)-(8R*,9S*,10S*)-8-HYDROXYMETHYL-9-(5-TERT.-BUTYL-DIMETHYLSILYLOXY-3-METHYL-1,3-PENTADIENYL)-3,3,8,10-TETRAMETHYL-1,5-DIOXASPIRO-[5,5]-UNDECA

Compound with spectra: 1 NMR

#26;(+/-)-9-(1E,3Z)-(8R*,9S*,10S*)-8-HYDROXYMETHYL-9-(5-TERT.-BUTYL-DIMETHYLSILYLOXY-3-METHYL-1,3-PENTADIENYL)-3,3,8,10-TETRAMETHYL-1,5-DIOXASPIRO-[5,5]-UNDECA
SpectraBase Compound ID KXdqHr6zKW5
InChI InChI=1S/C26H48O5Si/c1-20(12-14-31-32(9,10)22(3,4)5)11-13-26(28)21(2)15-25(16-24(26,8)17-27)29-18-23(6,7)19-30-25/h11-13,21,27-28H,14-19H2,1-10H3/b13-11+,20-12-/t21-,24+,26+/m1/s1
InChIKey SPLZJJAFUNIWFY-BWOAHZCNSA-N
Mol Weight 468.8 g/mol
Molecular Formula C26H48O5Si
Exact Mass 468.327101 g/mol
Enantiomer InChIKey SPLZJJAFUNIWFY-YTHBKYDPSA-N

View Spectrum of #26;(+/-)-9-(1E,3Z)-(8R*,9S*,10S*)-8-HYDROXYMETHYL-9-(5-TERT.-BUTYL-DIMETHYLSILYLOXY-3-METHYL-1,3-PENTADIENYL)-3,3,8,10-TETRAMETHYL-1,5-DIOXASPIRO-[5,5]-UNDECA

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
(1'R,2'R)-8'-HYDROXY-2',3'-DIHYDROABSCISIC ACID (HEMI-KETAL FORM)
(1'S,2'S)-8'-HYDROXY-2',3'-DIHYDROABSCISIC ACID (HEMI-KETAL FORM)
5,11-EPOXY-7,8-DEHYDRO-3,6,9-TRIHYDROXY-MEGASTIGMANE
2,4-Pentadienoic acid, 3-methyl-5-(1',5',5'-trimethylspiro[1,3-dioxolane-2,3'-[7]oxabicyclo[4.1.0]heptan]-6'-yl)-, methyl ester, [1'R-[1'.alpha.,6'.alpha.(2Z,4E)]]-
2,4-Pentadienoic acid, 3-methyl-5-(1',5',5'-trimethylspiro[1,3-dioxolane-2,3'-[7]oxabicyclo[4.1.0]hept]-6'-yl)-, methyl ester, [1'R-[1'.alpha.,6'.alpha.(2E,4E)]]-
Spiro[1,3-dioxolane-2,5'-[5H]inden]-1'(4'H)-one, 3'a,6',7',7'a-tetrahydro-3'a,7',7'a-trimethyl-, (3'a.alpha.,7'.alpha.,7'a.alpha.)-(.+-.)-
(-)-(3R,4S,E)-1-[(3a'S,4'R,5'R,6a'R)-5'-(tert-Butyldimethylsilyloxy)-5,5-dimethylhexahydro-1'H-spiro[1,3]dioxane-2,2'-pentalene]-4'-yl]-4-methyloct-1-en-6-yn-3-ol
Silane, (dichloromethyl)dimethyl[[(3.beta.,6E)-9,10-secocholesta-5(10),6,8(14)-trien-3-yl]oxy]-
Methyl (3a'S,4'R,5'R,6a'R)-5'-(tert-butyldimethylsilyloxy)-5,5-dimethylhexahydro-1'H-spiro[1,3]dioxane-2,2'-pentalene]-4'-carboxylate
(1R*,2R*/S*,6S*)-2,6-Dimethyl-5-oxabicyclo[4.4.0]decan-1-ol ethylene glycol acetal
Title Journal or Book Year
Oxidation of the 8′-position of a biologically active abscisic acid analogue Phytochemistry 1993
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