For citations & permissions, please see: Citations & Permissions - Wiley Science Solutions*

*Links on SpectraBase are not permalinks.

#26;(+/-)-9-(1E,3Z)-(8R*,9S*,10S*)-8-HYDROXYMETHYL-9-(5-TERT.-BUTYL-DIMETHYLSILYLOXY-3-METHYL-1,3-PENTADIENYL)-3,3,8,10-TETRAMETHYL-1,5-DIOXASPIRO-[5,5]-UNDECA

Compound with spectra: 1 NMR

#26;(+/-)-9-(1E,3Z)-(8R*,9S*,10S*)-8-HYDROXYMETHYL-9-(5-TERT.-BUTYL-DIMETHYLSILYLOXY-3-METHYL-1,3-PENTADIENYL)-3,3,8,10-TETRAMETHYL-1,5-DIOXASPIRO-[5,5]-UNDECA
SpectraBase Compound ID KXdqHr6zKW5
InChI InChI=1S/C26H48O5Si/c1-20(12-14-31-32(9,10)22(3,4)5)11-13-26(28)21(2)15-25(16-24(26,8)17-27)29-18-23(6,7)19-30-25/h11-13,21,27-28H,14-19H2,1-10H3/b13-11+,20-12-/t21-,24+,26+/m1/s1
InChIKey SPLZJJAFUNIWFY-BWOAHZCNSA-N
Mol Weight 468.8 g/mol
Molecular Formula C26H48O5Si
Exact Mass 468.327101 g/mol
Enantiomer InChIKey SPLZJJAFUNIWFY-YTHBKYDPSA-N

View Spectrum of #26;(+/-)-9-(1E,3Z)-(8R*,9S*,10S*)-8-HYDROXYMETHYL-9-(5-TERT.-BUTYL-DIMETHYLSILYLOXY-3-METHYL-1,3-PENTADIENYL)-3,3,8,10-TETRAMETHYL-1,5-DIOXASPIRO-[5,5]-UNDECA

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
(1'R,2'R)-8'-HYDROXY-2',3'-DIHYDROABSCISIC ACID (HEMI-KETAL FORM)
(1'S,2'S)-8'-HYDROXY-2',3'-DIHYDROABSCISIC ACID (HEMI-KETAL FORM)
5,11-EPOXY-7,8-DEHYDRO-3,6,9-TRIHYDROXY-MEGASTIGMANE
2,4-Pentadienoic acid, 3-methyl-5-(1',5',5'-trimethylspiro[1,3-dioxolane-2,3'-[7]oxabicyclo[4.1.0]hept]-6'-yl)-, methyl ester, [1'R-[1'.alpha.,6'.alpha.(2E,4E)]]-
2,4-Pentadienoic acid, 3-methyl-5-(1',5',5'-trimethylspiro[1,3-dioxolane-2,3'-[7]oxabicyclo[4.1.0]heptan]-6'-yl)-, methyl ester, [1'R-[1'.alpha.,6'.alpha.(2Z,4E)]]-
Spiro[1,3-dioxolane-2,5'-[5H]inden]-1'(4'H)-one, 3'a,6',7',7'a-tetrahydro-3'a,7',7'a-trimethyl-, (3'a.alpha.,7'.alpha.,7'a.alpha.)-(.+-.)-
(-)-(3R,4S,E)-1-[(3a'S,4'R,5'R,6a'R)-5'-(tert-Butyldimethylsilyloxy)-5,5-dimethylhexahydro-1'H-spiro[1,3]dioxane-2,2'-pentalene]-4'-yl]-4-methyloct-1-en-6-yn-3-ol
Silane, (dichloromethyl)dimethyl[[(3.beta.,6E)-9,10-secocholesta-5(10),6,8(14)-trien-3-yl]oxy]-
Methyl (3a'S,4'R,5'R,6a'R)-5'-(tert-butyldimethylsilyloxy)-5,5-dimethylhexahydro-1'H-spiro[1,3]dioxane-2,2'-pentalene]-4'-carboxylate
(1R*,2R*/S*,6S*)-2,6-Dimethyl-5-oxabicyclo[4.4.0]decan-1-ol ethylene glycol acetal
Title Journal or Book Year
Oxidation of the 8′-position of a biologically active abscisic acid analogue Phytochemistry 1993
Other Resources
Unknown Identification

Search your unknown spectrum against the world's largest collection of reference spectra

KnowItAll Campus Solutions

KnowItAll offers faculty and students at your school access to all the tools you need for spectral analysis and structure drawing & publishing! Plus, access the world's largest spectral library.