#18A;N'-[(1R,(2E),3AS,4R,5R,6AS)-4-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-1-METHYLHEXAHYDROPENTALEN-2(1H)-YLIDENE]-4-METHYLBENZENESULFONOHYDRAZIDE
Compound with spectra: 1 NMR
![#18A;N'-[(1R,(2E),3AS,4R,5R,6AS)-4-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-1-METHYLHEXAHYDROPENTALEN-2(1H)-YLIDENE]-4-METHYLBENZENESULFONOHYDRAZIDE](/api/compound/KLTsVQJJ8Kv.png?ph=true&h=300&w=458 "#18A;N'-[(1R,(2E),3AS,4R,5R,6AS)-4-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-1-METHYLHEXAHYDROPENTALEN-2(1H)-YLIDENE]-4-METHYLBENZENESULFONOHYDRAZIDE")
| SpectraBase Compound ID | KLTsVQJJ8Kv |
|---|---|
| InChI | InChI=1S/C35H44N2O3SSi/c1-7-14-30-32-23-33(36-37-41(38,39)27-21-19-25(2)20-22-27)26(3)31(32)24-34(30)40-42(35(4,5)6,28-15-10-8-11-16-28)29-17-12-9-13-18-29/h7-13,15-22,26,30-32,34,37H,1,14,23-24H2,2-6H3/b36-33+/t26-,30-,31-,32-,34-/m1/s1 |
| InChIKey | AROFSCJBAALFKX-NFJNVBBBSA-N |
| Mol Weight | 600.9 g/mol |
| Molecular Formula | C35H44N2O3SSi |
| Exact Mass | 600.284191 g/mol |
| Enantiomer InChIKey | AROFSCJBAALFKX-MIFMDYIHSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
Methyl 7-{1-[(1R,2R,4aR,6R,8S,8aS)-6-[(tert-butydiphenylsilyl)oxy]-8-[(2S)-methyl-1-oxobutyl)oxy]-1,2,4a,5,6,7,8,8a-octahydro-2-methylnaphthalenyl]}-3(R)-[(tert-butyldimethylsilyl)oxy]-5-oxohepten-6-oate
2.beta.-Methyl-19-nor-1.alpha.,25-dihydroxyvitamin D3 - 3-[(t-butyl)diphenylsilyl] - derivative
2.alpha.-Methyl-19-nor-1.alpha.,25-dihydroxyvitamin D3 - 1-[(t-butyl)diphenylsilyl] - derivative
(2R,3R,5S)-2-Allyl-3-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-2-(2-methoxyethoxymethoxy)cyclohexanone
(1S)-1-(1"-Acetyloxy-2"-octenyl)-5-[(1',1'-dimethylethyl)diphenylsilyloxy]octahydro-2-pentalenyl acetate
(1R,3AR,4R,5R,6AS)-1,4-DIALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-HEXAHYDROPENTALEN-2(1H)-ONE
3,4-BIS-O-(TERT.-BUTYLDIPHENYLSILYL)-6-DEOXY-2-PHENYLSELENO-BETA-L-GLUCO-PYRANOSE
(2S)-2-[(2S,4Z)-4-[(2S)-3-[tert-butyl(diphenyl)silyl]oxy-2-methyl-propylidene]-5-keto-2-methyl-tetrahydrofuran-2-yl]pyrrolidine-1-carboxylic acid tert-butyl ester
N-{(3'aS,4'R,6'aR)-4'-[4-(S)-1'-(oxyhexyl)phenyl]-1',6'a',6',3'a-tetrahydro-5,5-dimethylspiro[1,3-dioxane-2,2'-(1'H)-pentalen])-5'-ylidene}-N'-(p-toluenesulfonyl)-hydrazine
#3;[(2R,3S,5R)-3-(TERT.-BUTYL-DIPHENYL-SILANYLOXY)-5-(5-METHYL-2,4-DIOXO-3,4-DIHYDRO-2H-PYRIMIDIN-1-YL)-TETRAHYDROFURAN-2-YLETHYNYL]-PHOSPHONIC-ACID-DIMETHYLES
| Title | Journal or Book | Year |
|---|---|---|
| Doing it Twice: Asymmetric Deprotonation/Alkylation of Weiss Diketone Derivatives as Key Steps in the Functionalization of Bicyclo[3.3.0]octanes | European Journal of Organic Chemistry | 2012 |