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Diethyl N-[(1R,4R)-2-Bornylidene]-3-[(S)-1,3-dioxolan-4-yl]-(2R,3R)-glutamate

Compound with spectra: 1 NMR

Diethyl N-[(1R,4R)-2-Bornylidene]-3-[(S)-1,3-dioxolan-4-yl]-(2R,3R)-glutamate
SpectraBase Compound ID K7smPMUm9yI
InChI InChI=1S/C22H35NO6/c1-6-27-18(24)11-15(16-12-26-13-29-16)19(20(25)28-7-2)23-17-10-14-8-9-22(17,5)21(14,3)4/h14-16,19H,6-13H2,1-5H3/b23-17+/t14?,15-,16?,19-,22?/m0/s1
InChIKey OKBSSKAQILCYDP-MOCSXLHISA-N
Mol Weight 409.5 g/mol
Molecular Formula C22H35NO6
Exact Mass 409.246438 g/mol
Enantiomer InChIKey OKBSSKAQILCYDP-LMFIUWLOSA-N

View Spectrum of Diethyl N-[(1R,4R)-2-Bornylidene]-3-[(S)-1,3-dioxolan-4-yl]-(2R,3R)-glutamate

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
Diethyl N-[(1R,4R)-2-Bornylidene]-3-[(S)-1,3-dioxolan-4-yl]-(2R,3R)-glutamate
tert-Butyl 1,1-dimethyl (2R,3R)-3-[(1R,4R)-bornylideneamino]-2-[(E)-2-phenylvinyl]-1,1,3-propanetricarboxylate
tert-Butyl 1,1-dimethyl (2R,3R)-3-[(1R,4R)-bornylideneamino]-2-[(E)-2-methoxylvinyl]-1,1,3-propanetricarboxylate
(S)-N-tert-Butyl-{2-[(1-(tert-butyloxycarbonyl)-2-phenylethyl-imino)-7,7-dimethylcyclo[2.2.1]heptyl-1yl]methyl}sulfonamide
N-Cyclohexyl-10-[2-(1-(tert-butyloxycarbonyl)butyl)imino-7,7-dimethylcyclo[2.2.1]heptyl)methyl]sulfonamide isomer
(+)-N-Cyclohexyl-10-[2-(1-(tert-butyloxycarbonyl)butyl)imino-7,7-dimethylcyclo[2.2.1]heptyl)methyl]sulfonamide
ZAKKVLDIKTYRCK-ZBJSNUHESA-N
SYMBIOIMINE
(1S,4S,7S)-7-HYDROXYFENCHAN-2-ONE-7-O-BETA-D-GLUCOPYRANOSIDE
CHLORO(TRIPHENYLPHOSPHINE)BIS[PHENYL(2,4,6-TRI-TERT-BUTYLPHENYLIMINO)PHOSPHINE]RHODIUM
2-Pentenoic acid, 3-methyl-5-[octahydro-5',5',8'a-trimethyl-7'-[(methylthio)thioxomethoxy]spiro[1,3-dioxolane-2,2'(1'H)-naphthalen]-1'-yl]-, methyl ester, [1'S-[1'.alpha.(E),4'a.beta.,7'.beta.,8'a.alp ha.]]-
Title Journal or Book Year
Double chiral induction in ul-selective Michael additions of metal enolates of N-bornylideneglycinates to (E)-4,5-dioxy-2-pentenoates. Exclusive ul,lk-1,2-chiral induction leading to l,u-Michael adducts The Journal of Organic Chemistry 1993
Diethyl N-[(1R,4R)-2-Bornylidene]-3-[(S)-1,3-dioxolan-4-yl]-(2R,3R)-glutamate
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