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METHYL-3-O-BENZOYL-6-O-(TERT.-BUTYLDIPHENYLSILYL)-2,4-DIDEOXY-4-C-[Z-(METHOXYCARBONYL)-METHYLENE]-ALPHA-D-ERYTHRO-HEXOPYRANOSIDE

Compound with spectra: 1 NMR

METHYL-3-O-BENZOYL-6-O-(TERT.-BUTYLDIPHENYLSILYL)-2,4-DIDEOXY-4-C-[Z-(METHOXYCARBONYL)-METHYLENE]-ALPHA-D-ERYTHRO-HEXOPYRANOSIDE
SpectraBase Compound ID K7fyQD4osUI
InChI InChI=1S/C33H38O7Si/c1-33(2,3)41(25-17-11-7-12-18-25,26-19-13-8-14-20-26)38-23-29-27(21-30(34)36-4)28(22-31(37-5)39-29)40-32(35)24-15-9-6-10-16-24/h6-21,28-29,31H,22-23H2,1-5H3/b27-21+/t28-,29+,31-/m0/s1
InChIKey LLRKZAZKBWSEIO-CQCCSGGSSA-N
Mol Weight 574.7 g/mol
Molecular Formula C33H38O7Si
Exact Mass 574.23868 g/mol
Enantiomer InChIKey LLRKZAZKBWSEIO-WNSDMZJYSA-N

View Spectrum of METHYL-3-O-BENZOYL-6-O-(TERT.-BUTYLDIPHENYLSILYL)-2,4-DIDEOXY-4-C-[Z-(METHOXYCARBONYL)-METHYLENE]-ALPHA-D-ERYTHRO-HEXOPYRANOSIDE

13C NMR Spectrum
Copyright Copyright © 2016-2025 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
METHYL-3-O-BENZOYL-6-O-(TERT.-BUTYLDIPHENYLSILYL)-2,4-DIDEOXY-4-C-[E-(METHOXYCARBONYL)-METHYLENE]-ALPHA-D-ERYTHRO-HEXOPYRANOSIDE
METHYL-3-O-BENZOYL-6-O-(TERT.-BUTYLDIPHENYLSILYL)-2,4-DIDEOXY-4-C-[(METHOXYCARBONYL)-METHYL]-ALPHA-D-RIBO-HEXOPYRANOSIDE
(2R,3R,5R,6S)-5-(Benzoyloxy)-6-[(tert-butyldiphenylsiloxy)methyl]-2-[(methoxycarbonyl)methyl]tetrahydropyran-3-yl Benzoate
(E)-ethyl 3-((3aS,4R,6S,7aS)-6-(((tert-butyldiphenylsilyl)oxy)methyl)-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-4-yl)acrylate
tert-Butyl(((3aS,4R,6S,7aS)-4-((E)-3-((4-methoxybenzyl)oxy)prop-1-en-1-yl)-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-6-yl)methoxy)diphenylsilane
1,7-Dioxaspiro[5.5]undecan-4-ol, 2-[6-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-3,5-dimethyl-2-hexenyl]-8,9-dimethyl-, benzoate, [2R-[2.alpha.(2E,5R*),4.alpha.,6.beta.(8R*,9S*)]]-
2,3,4-TRI-O-BENZYL-1-O-(2'-O-(BENZYLOXY-METHYL)-5'-O-(TERT.-BUTYL-DIPHENYLSILYL)-BETA-D-RIBOFURANOSYL)-5-O-(TRANS-PROPEN-1-YL)-D-RIBITOL
INTERMEDIATE-B
(6R,8R)-8-((2R,4R,5R)-5-(2-(Benzyloxy)ethyl)-4-methyltetrahydrofuran-2-yl)-2,2,11,11-tetramethyl-3,3,10,10-tetraphenyl-4,9-dioxa-3,10-disiladodecan-6-yl isobutyrate
compoound17
Title Journal or Book Year
Total synthesis of (+)-thromboxane B2 from D-glucose. A detailed account Canadian Journal of Chemistry 1981
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