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1,3:4,6-DI-O-BENZYLIDENE-2-O-(1-NAPHTHYLMETHYL)-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL

Compound with spectra: 4 NMR

1,3:4,6-DI-O-BENZYLIDENE-2-O-(1-NAPHTHYLMETHYL)-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL
SpectraBase Compound ID JNxjSqbSEiV
InChI InChI=1S/C51H41O8P/c1-3-17-36(18-4-1)50-53-31-44(52-30-38-22-13-21-33-14-7-10-23-39(33)38)48(55-50)49-45(32-54-51(56-49)37-19-5-2-6-20-37)59-60-57-42-28-26-34-15-8-11-24-40(34)46(42)47-41-25-12-9-16-35(41)27-29-43(47)58-60/h1-29,44-45,48-51H,30-32H2/t44-,45-,48-,49-,50?,51?/m1/s1
InChIKey JAHSUZVIFCAIOP-RZSHCYCQSA-N
Mol Weight 812.9 g/mol
Molecular Formula C51H41O8P
Exact Mass 812.253905 g/mol
Enantiomer InChIKey JAHSUZVIFCAIOP-SUMFPQEZSA-N

View Spectrum of 1,3:4,6-DI-O-BENZYLIDENE-2-O-(1-NAPHTHYLMETHYL)-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL

31P NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent DMSO-D6

View Spectrum of 1,3:4,6-DI-O-BENZYLIDENE-2-O-(1-NAPHTHYLMETHYL)-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL

31P NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent DMSO-D6

View Spectrum of 1,3:4,6-DI-O-BENZYLIDENE-2-O-(1-NAPHTHYLMETHYL)-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent DMSO-D6

View Spectrum of 1,3:4,6-DI-O-BENZYLIDENE-2-O-(1-NAPHTHYLMETHYL)-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent DMSO-D6
1,3:4,6-DI-O-BENZYLIDENE-2-O-DIPHENYLMETHYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL
KBGDJOYOTSABRH-QOKPJABCSA-N
KBGDJOYOTSABRH-URHSQPNTSA-N
KBGDJOYOTSABRH-JUZFRHFMSA-N
KBGDJOYOTSABRH-NWQMJODPSA-N
KBGDJOYOTSABRH-YXRRNMOASA-N
XACJUAAQAXGWQD-YXRRNMOASA-N
3-[(R)-(1,1'-BINAPHTHYL-2,2'-DIYL)]-PHOSPHITE-5-DEOXY-1,2-O-ISOPROPYLIDENE-5-DIPHENYLPHOSPHINE-ALPHA-D-XYLOFURANOSE
SYFZFCGJDKTBGT-UHFFFAOYSA-N
IJUNSDKDQASREW-UHFFFAOYSA-N
Title Journal or Book Year
A Novel Class of P−O Monophosphite Ligands Derived from d-Mannitol:  Broad Applications in Highly Enantioselective Rh-Catalyzed Hydrogenations The Journal of Organic Chemistry 2004
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