RAC-(1R,2R)-1-[3-[(TERT.-BUTYLDIPHENYLSILYL)-OXY]-PROPYL]-2-[(S)-1-DIMETHYL-(PHENYL)-SILYL]-2-(HYDROXYETHYL)-2-(HYDROXYMETHYL)-CYCLOPENTANOL
Compound with spectra: 1 NMR
![RAC-(1R,2R)-1-[3-[(TERT.-BUTYLDIPHENYLSILYL)-OXY]-PROPYL]-2-[(S)-1-DIMETHYL-(PHENYL)-SILYL]-2-(HYDROXYETHYL)-2-(HYDROXYMETHYL)-CYCLOPENTANOL](/api/compound/IOraf7l5NcF.png?ph=true&h=300&w=458 "RAC-(1R,2R)-1-[3-[(TERT.-BUTYLDIPHENYLSILYL)-OXY]-PROPYL]-2-[(S)-1-DIMETHYL-(PHENYL)-SILYL]-2-(HYDROXYETHYL)-2-(HYDROXYMETHYL)-CYCLOPENTANOL")
| SpectraBase Compound ID | IOraf7l5NcF |
|---|---|
| InChI | InChI=1S/C35H50O4Si2/c1-33(2,3)41(30-19-11-7-12-20-30,31-21-13-8-14-22-31)39-26-16-25-35(38)24-15-23-34(35,28-37)32(27-36)40(4,5)29-17-9-6-10-18-29/h6-14,17-22,32,36-38H,15-16,23-28H2,1-5H3/t32-,34+,35-/m1/s1 |
| InChIKey | UTZSJMRFYPLHRO-VXMNRCMCSA-N |
| Mol Weight | 591.0 g/mol |
| Molecular Formula | C35H50O4Si2 |
| Exact Mass | 590.324763 g/mol |
| Enantiomer InChIKey | UTZSJMRFYPLHRO-MKTDKWDHSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
#8A;ANTI-(2R,3R)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S)-2-(METHOXYCARBONYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-METHYL-4-PENTENONE-
#9A;ANTI-(2S,3S)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S)-2-(METHOXYCARBONYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-METHYL-4-PENTENONE-
#10H;(2,3-SYN-1):(2R,3S)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,4R)-4-METHOXY-2-(METHOXYMETHYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-
#9H;MINOR-(2,3-ANTI):(2S,3S)-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,4R)-4-METHOXY-2-(METHOXYMETHYL)-PYRROLIDIN-1-YL]-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL
(3R)-1-[(1R)-2-[tert-butyl(diphenyl)silyl]oxy-1-phenyl-ethyl]-4,4-diethoxy-N-[(2-methoxyphenyl)methyl]piperidin-3-amine
Tert-Butyl(((3aR,4R,6S,6aS)-2,2-dimethyl-6-phenyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methoxy)diphenylsilane
Tert-Butyl(((3aS,4R,6R,6aR)-2,2-dimethyl-6-phenyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methoxy)diphenylsilane
(Z)-1-[Benzyl-2-[(t-butyldiphenylsilyl)oxymethyl]-4-[(isopropenylpyrrolidinyl)ethenyl] Diisopropylcarbamate
(Z)-2-[(2S,3S,4R)-1-BENZYL-2-([[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-METHYL)-4-ISOPROPENYLPYRROLIDINYL]-ETHENYL-DIISOPROPYLCARBAMATE
(Z)-2-[(2S,3R,4S)-1-BENZYL-2-([[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-METHYL)-4-ISOPROPENYLPYRROLIDINYL]-ETHENYL-DIISOPROPYLCARBAMATE
| Title | Journal or Book | Year |
|---|---|---|
| Development of an additive-controlled, SmI2-mediated stereoselective sequence: Telescoped spirocyclisation, lactone reduction and Peterson elimination | Beilstein Journal of Organic Chemistry | 2013 |