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(-)-PINOLIDOXIN

Compound with spectra: 3 NMR

(-)-PINOLIDOXIN
SpectraBase Compound ID HzW59hLtW1Y
InChI InChI=1S/C18H26O6/c1-3-5-6-12-16(20)23-15-11-8-7-10-13(19)17(21)14(9-4-2)24-18(15)22/h3,5-7,10,12-15,17,19,21H,4,8-9,11H2,1-2H3/b5-3+,10-7+,12-6+/t13-,14+,15-,17-/m1/s1
InChIKey TXPRZPDVUZCNLB-OPFKWUSQSA-N
Mol Weight 338.4 g/mol
Molecular Formula C18H26O6
Exact Mass 338.172939 g/mol
Enantiomer InChIKey TXPRZPDVUZCNLB-PREDPWABSA-N

View Spectrum of (-)-PINOLIDOXIN

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3

View Spectrum of (-)-PINOLIDOXIN

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent Unknown

View Spectrum of (-)-PINOLIDOXIN

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
  • TXPRZPDVUZCNLB-OPFKWUSQSA-N
PINOLIDOXIN
TXPRZPDVUZCNLB-PXTUIATNSA-N
(2E,4E)-hexa-2,4-dienoic acid [(3S,6E,8S,9S,10R)-8,9-dihydroxy-2-keto-10-propyl-3,4,5,8,9,10-hexahydrooxecin-3-yl] ester
5,6-DIHYDRO-PINOLIDOXIN;2-(2,4-HEXADIENOYLOXY)-7,8-DIHYDROXY-9-PROPYLNONAN-9-OLIDE
rac-3-endo-Acetoxy-7-oxabicyclo[2.2.1]hept-5-en-2-endo-yl Hept-6-enoate
[(2R,3aR,8aR)-5-oxidanylidene-3,3a,8,8a-tetrahydro-2H-furo[3,2-b]oxepin-2-yl]methyl benzoate
(1R,5R,6R)-6-HEPTYL-2,7-DIOXA-BICYCLO-[3.3.0]-OCTAN-3,8-DIONE
(3aR,4S,6aR)-4-octyl-3,3a,4,6a-tetrahydrofuro[2,3-c]furan-2,6-dione
(3aS,4R,6aR)-4-Octyldihydrofuro[3,4-b]furan-2,6-dione
1(R,S)-6(R,S)-Octyl-2,7-dioxa-bicyclo(3.3.0)oct-3,8-dione
Title Journal or Book Year
Total Syntheses of the Phytotoxic Lactones Herbarumin I and II and a Synthesis-Based Solution of the Pinolidoxin Puzzle Journal of the American Chemical Society 2002
Synthesis of (−)-Pinolidoxin:  Divergent Synthetic Strategy Exploiting a Common Silacyclic Precursor Organic Letters 2002

This compound is available in the following databases:

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