(S)-1-[(2S,3R,4R,6S)-4-(DIMETHYLPHENYLSILYL)-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXYBENZYL-OXY)-ETHAN-1-OL
Compound with spectra: 1 NMR
![(S)-1-[(2S,3R,4R,6S)-4-(DIMETHYLPHENYLSILYL)-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXYBENZYL-OXY)-ETHAN-1-OL](/api/compound/HAcE3fkTFrd.png?ph=true&h=300&w=458 "(S)-1-[(2S,3R,4R,6S)-4-(DIMETHYLPHENYLSILYL)-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXYBENZYL-OXY)-ETHAN-1-OL")
| SpectraBase Compound ID | HAcE3fkTFrd |
|---|---|
| InChI | InChI=1S/C26H34O5Si/c1-6-20-16-24(32(4,5)22-10-8-7-9-11-22)25(26(29-3)31-20)23(27)18-30-17-19-12-14-21(28-2)15-13-19/h1,7-15,20,23-27H,16-18H2,2-5H3/t20-,23-,24-,25+,26+/m1/s1 |
| InChIKey | ARCYLFPHRAFBHK-SWOLCGDXSA-N |
| Mol Weight | 454.6 g/mol |
| Molecular Formula | C26H34O5Si |
| Exact Mass | 454.217551 g/mol |
| Enantiomer InChIKey | ARCYLFPHRAFBHK-OZJWZVNMSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
#46B;(S)-2-[(2S,3S,4R,6S)-4-[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)-SILOXY]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-HYDROXYETHYL-PARA-TOLUENESULFONAT
(+/-)-(4-(Dimethyl(phenyl)silyl)-5-((dimethyl(phenyl)silyl)methyl)tetrahydrofuran-2-yl)(phenyl)methanone
6-O-Benzyl-3-deoxy-1,2-O-isopropylidene-3-C-[2-(4-methoxybenzyloxy)ethyl]-5-O-methyl-.beta.-L-talofuranose
4A-METHYL-2-PHENYL-1,3-DIOXOLO-[4,5-F]-PERHYDROISOBENZOFURAN-5-ON
1H-2-Benzopyran-6-acetic acid, octahydro-5,7-dihydroxy-3-methoxy-8a-[(phenylmethoxy)methyl]-, methyl ester, (3.alpha.,4a.alpha.,5.alpha.,6.beta.,7.alpha.,8a.alpha.)-(.+-.)-
(1RS,2RS)-1,8,8-TRIMETHYL-1-(2'-TERT.-BUTYL-DIMETHYLSILYLOXYETHYL)-6,10-DIOXASPIRO-[4.5]-DEC-2-YL-BENZOATE
(1RS,2SR)-1,8,8-trimethyl-1-(2'-t-butyldimethylsilyloxyethyl)-6,10-dioxaspiro[4.5]dec-2-yl benzoate
EPIDERMIN-TETRA-(TRIMETHYLSILYLYOXY);3-BETA-D-GLUCOPYRANOSYLOXY-3-METHYL-BUTYRONITRILE-TETRA-(TRIMETHYLSILYLOXY)
(5S,4R)-(S)-tert-Butyl 2-[1-methoxy-2-(2,2,4-trimethyl-1,3-dioxolan-5-yl)-2-(p-methoxybenzoxy)ethyl]cyclopropane-1-carboxylate
{(2S,3R)-2-[(R)-(4-Methoxy-benzyloxy)-((4S,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-methyl]-5-oxo-tetrahydro-furan-3-yl}-acetic acid tert-butyl ester
| Title | Journal or Book | Year |
|---|---|---|
| Stereocontrolled Synthesis of a Cn-Cn+7Building Block (“Eastern Moiety”) for the Unnatural Enantiomers of Important Polyol,Polyene Antibiotics Based on a Ring-Closing Metathesis and an Aldol Addition of a Lactone Enolate | European Journal of Organic Chemistry | 2013 |