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(1SR,5SR,7RS,8SR)-7-tert-Butyldimethylsilyloxy-8-cyanobicyclo[3.3.0]octan-2-one

Compound with spectra: 1 NMR, and 1 MS (GC)

(1SR,5SR,7RS,8SR)-7-tert-Butyldimethylsilyloxy-8-cyanobicyclo[3.3.0]octan-2-one
SpectraBase Compound ID Gmeb9RGD7zW
InChI InChI=1S/C15H25NO2Si/c1-15(2,3)19(4,5)18-13-8-10-6-7-12(17)14(10)11(13)9-16/h10-11,13-14H,6-8H2,1-5H3/t10-,11-,13+,14-/m0/s1
InChIKey VEXNNWPRNCSRQA-VTPLQMEGSA-N
Mol Weight 279.45 g/mol
Molecular Formula C15H25NO2Si
Exact Mass 279.165456 g/mol
Enantiomer InChIKey VEXNNWPRNCSRQA-MHDGFBEUSA-N

View Spectrum of (1SR,5SR,7RS,8SR)-7-tert-Butyldimethylsilyloxy-8-cyanobicyclo[3.3.0]octan-2-one

MS (GC) Spectrum
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Source of Spectrum KC-0-2676-12

View Spectrum of (1SR,5SR,7RS,8SR)-7-tert-Butyldimethylsilyloxy-8-cyanobicyclo[3.3.0]octan-2-one

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
8-BETA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-ANDROSTAN-17-ONE
(1R,2R,3R)-(-)-3-[3-(tert-Butyldimethylsiloxy)-1,2-dimethyl-6-oxocyclohexyl]propionic acid methyl ester
Cyclopentaneacetic acid, 2-(dimethoxymethyl)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-5-hydroxy-, methyl ester, (1.alpha.,2.beta.,3.beta.,5.beta.)-(.+-.)-
(1.beta.,2.alpha.,6.alpha.,8.beta.)-4,4-Dimethyl-3,5-dioxatricyclo[6.3.0.0(2,6)]undecan-11-one
(1R,2S,4aR,8S,8aS)-2-methyl-8-tri(propan-2-yl)silyloxy-1,2,4a,5,6,7,8,8a-octahydronaphthalene-1-carbaldehyde
ETHYL-(18E)-20-(17->18)-ABEO-8-ALPHA-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-DE-A,B-PREGN-18-EN-21-ATE
JQYCUZSNFCTKQC-AZKZNFPZSA-N
(1-S,2-S,3-R,4-R,6-R)-4-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-1,3-DIMETHYL-7-OXABICYCLO-[4.1.0]-HEPTAN-1-OL
Methyl syn-(+,-)-9-oxo-11.alpha.,15.alpha.,19.alpha./.beta.-tris(trimethylsyloxy)prost-13-trans-enoate methyl oxime
Methyl anti-(+,-)-9-oxo-11.alpha.,15.alpha.,19.alpha./.beta.-tris(trimethylsiloxy)prost-13-trans-enoate methyl oxime
Title Journal or Book Year
Stereocontrol in organic synthesis using silicon-containing compounds. A synthesis of a (±)-carbacyclin analogue with the geometry of the exocyclic double bond controlled by the protodesilylation of an allylsilane Journal of the Chemical Society, Perkin Transactions 1 1998
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