(+)-METHYL-(3S,4S,5S,7R,9S,10R,11R)-9-HYDROXY-4-METHYL-5-TRIISOPROPYLSILANYLOXY-BICYCLOMETHANO-[1(10,11)]-OXA-[1(3,7)]-DODECANOATE
Compound with spectra: 1 NMR
![(+)-METHYL-(3S,4S,5S,7R,9S,10R,11R)-9-HYDROXY-4-METHYL-5-TRIISOPROPYLSILANYLOXY-BICYCLOMETHANO-[1(10,11)]-OXA-[1(3,7)]-DODECANOATE](/api/compound/GM5RGIC53To.png?ph=true&h=300&w=458 "(+)-METHYL-(3S,4S,5S,7R,9S,10R,11R)-9-HYDROXY-4-METHYL-5-TRIISOPROPYLSILANYLOXY-BICYCLOMETHANO-[1(10,11)]-OXA-[1(3,7)]-DODECANOATE")
| SpectraBase Compound ID | GM5RGIC53To |
|---|---|
| InChI | InChI=1S/C24H46O5Si/c1-14(2)30(15(3)4,16(5)6)29-23-12-19(11-21(25)20-10-17(20)7)28-22(18(23)8)13-24(26)27-9/h14-23,25H,10-13H2,1-9H3/t17-,18+,19-,20-,21+,22+,23+/m1/s1 |
| InChIKey | ARYVRTCASDBCCO-BWTXDCIASA-N |
| Mol Weight | 442.7 g/mol |
| Molecular Formula | C24H46O5Si |
| Exact Mass | 442.311451 g/mol |
| Enantiomer InChIKey | ARYVRTCASDBCCO-JZMXJYMNSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
#15;(-)-(3S,4S,5S,7R,9S,10R,11R,3'S,4'S,5'S,7'R,9'S,10'R,11'R)-4,4'-DIMETHYL-9,9'BIS-(2-METHYLCYCLOPROPYL)-5,5'-BIS-HYDROXY-15,16,15',16'-TETRAOXYTRICYCLO-[15.
(2S,4R,6R)-4-tert-Butyldimethylsiloxy-6-[(S)-2,3-dimethylpropyl]-tetrahydro-5,5-dimethyl-2H-pyran-2-carbonitrile
Cyclopentaneacetic acid, 2-(dimethoxymethyl)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-5-hydroxy-, methyl ester, (1.alpha.,2.beta.,3.beta.,5.beta.)-(.+-.)-
3-[(1S,2S,4aR,8S,8aS)-2-methyl-8-tri(propan-2-yl)silyloxy-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]-1-propanol
(1R,2S,4aR,8S,8aS)-2-methyl-8-tri(propan-2-yl)silyloxy-1,2,4a,5,6,7,8,8a-octahydronaphthalene-1-carbaldehyde
(1S,3S,5S,6S)-3-[(TERT.-BUTYLDIMETHYLSILOXY)-METHYL]-5-(METHOXYMETHOXY)-2-OXA-BICYCLO-[4.2.0]-OCTAN-7-ONE
3-Methoxy-18-methyl-13-[(E)-4'-methylpent-1'-enyl]-12,19,20-trioxatricylo[13.3.1.1(5,9)]icosane-7,11-dione
Methyl 2-[3-hydroxy-4-benzyloxy-5-((tert-butyldimethylsilyl)methyl)tetrahydrofuran-2-yl]ethanoate
(1-S,2-S,3-R,4-R,6-R)-4-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-1,3-DIMETHYL-7-OXABICYCLO-[4.1.0]-HEPTAN-1-OL
[(4R,6S)-6-[(S)-2-(TERT.-BUTYLDIMETHYLSILOXY)-1-[(R)-OXIRAN-2-YL]-ETHYL]-2,2-DIETHYL-1,3-DIOXAN-4-YL]-METHANOL
| Title | Journal or Book | Year |
|---|---|---|
| Total Synthesis of the Marine Natural Product (−)-Clavosolide A | Organic Letters | 2006 |