(2S,4R)-1-[(E)-6-(TERT.-BUTYLDIPHENYLSILYLOXY)-2-METHYLHEX-2-ENYL]-2-(HYDROXYMETHYL)-4-(METHOXYMETHYLOXY)-PYRROLIDINE
Compound with spectra: 1 NMR
![(2S,4R)-1-[(E)-6-(TERT.-BUTYLDIPHENYLSILYLOXY)-2-METHYLHEX-2-ENYL]-2-(HYDROXYMETHYL)-4-(METHOXYMETHYLOXY)-PYRROLIDINE](/api/compound/GJMpYdcqXpR.png?ph=true&h=300&w=458 "(2S,4R)-1-[(E)-6-(TERT.-BUTYLDIPHENYLSILYLOXY)-2-METHYLHEX-2-ENYL]-2-(HYDROXYMETHYL)-4-(METHOXYMETHYLOXY)-PYRROLIDINE")
| SpectraBase Compound ID | GJMpYdcqXpR |
|---|---|
| InChI | InChI=1S/C30H45NO4Si/c1-25(21-31-22-27(34-24-33-5)20-26(31)23-32)14-12-13-19-35-36(30(2,3)4,28-15-8-6-9-16-28)29-17-10-7-11-18-29/h6-11,14-18,26-27,32H,12-13,19-24H2,1-5H3/b25-14+/t26-,27+/m0/s1 |
| InChIKey | ADHYNRLHYGAVAY-GQRDADOASA-N |
| Mol Weight | 511.8 g/mol |
| Molecular Formula | C30H45NO4Si |
| Exact Mass | 511.311785 g/mol |
| Enantiomer InChIKey | ADHYNRLHYGAVAY-VXMLXUOASA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
4(S)-1-((tert-Butyldiphenylsilyl)oxy)-4-[1(S)-1-(4(R)-2,2-dimethyl[1,3]dioxolan-4-yl])propoxy]-7-(tolyl-4-sulfonyl)heptane
(2S)-5-[tert-butyl(diphenyl)silyl]oxy-2-[(1S)-1-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]propoxy]-1-pentanol
5-[7-(t-Butyldiphenylsilyloxy)hept-2-enyl]furo[2,3-b]pyridine
(E)-8-[(tert-Butyldiphenylsilyl)oxy]-5-methyl-1,3-diphenyl-4-octen-1-one
Ethyl 4(S)-7-((tert-Butyldiphenylsilyl)oxy)-4-[1(S)-1-(4(R)-2,2-dimethyl[1,3]dioxolan-4-yl]propoxy]heptanoate
Benzyl (2R,4S)-6-tert-Butyldiphenylsilyloxy-2,4-di-O-isopropylidene hexyl ether
Ethyl (6R,8S)-10-tert-Butyldiphenylsilyloxy-6,8-di-O-isopropylidenedeca-2,4-dienoate
2-BENZYL-6-[3-(TERT.-BUTYLDIPHENYLSILYLOXY)-PROPYL]-PYRIDAZIN-3(2H)-ONE
(2S,5R,7S)-7-[2'-(t-Butyldiphenylsilyloxy)ethyl]-2-methyl-1,6-dioxaspiro[4.5]decane
(2R,5S,7S)-7-[2'-(t-Butyldiphenylsilyloxy)ethyl]-2-methyl-1,6-dioxaspiro[4.5]decane
| Title | Journal or Book | Year |
|---|---|---|
| Zwitterionic Aza-Claisen Rearrangements Controlled by Pyrrolidine Auxiliaries - Useful Key Steps in Convergent Enantioselective Syntheses | European Journal of Organic Chemistry | 2012 |