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#7;[2A-R-(4-BETA,4A-ALPHA,5-BETA,6-ALPHA,7A-ALPHA,7B-BETA)]-4,5-DIACETYLOXY-6-(ACETYLOXYMETHYL)-2A,3,4,4A,5,6,7A,7B-OCTAHYDRO-2H-1,7-DIOXACYCLOPENT-[CD]-INDENE

Compound with spectra: 1 NMR, and 1 MS (GC)

#7;[2A-R-(4-BETA,4A-ALPHA,5-BETA,6-ALPHA,7A-ALPHA,7B-BETA)]-4,5-DIACETYLOXY-6-(ACETYLOXYMETHYL)-2A,3,4,4A,5,6,7A,7B-OCTAHYDRO-2H-1,7-DIOXACYCLOPENT-[CD]-INDENE
SpectraBase Compound ID FltuSAft4L2
InChI InChI=1S/C16H22O8/c1-7(17)20-6-12-15(23-9(3)19)14-11(22-8(2)18)4-10-5-21-16(24-12)13(10)14/h10-16H,4-6H2,1-3H3/t10-,11-,12+,13+,14-,15+,16-/m0/s1
InChIKey GIXSNOAEEHRTLI-DUMGAFKDSA-N
Mol Weight 342.34 g/mol
Molecular Formula C16H22O8
Exact Mass 342.131468 g/mol
Enantiomer InChIKey GIXSNOAEEHRTLI-XMDUCEHWSA-N

View Spectrum of #7;[2A-R-(4-BETA,4A-ALPHA,5-BETA,6-ALPHA,7A-ALPHA,7B-BETA)]-4,5-DIACETYLOXY-6-(ACETYLOXYMETHYL)-2A,3,4,4A,5,6,7A,7B-OCTAHYDRO-2H-1,7-DIOXACYCLOPENT-[CD]-INDENE

MS (GC) Spectrum
Copyright Copyright © 2020-2024 John Wiley & Sons, Inc. All Rights Reserved.
Source of Spectrum J-64-8309-7

View Spectrum of #7;[2A-R-(4-BETA,4A-ALPHA,5-BETA,6-ALPHA,7A-ALPHA,7B-BETA)]-4,5-DIACETYLOXY-6-(ACETYLOXYMETHYL)-2A,3,4,4A,5,6,7A,7B-OCTAHYDRO-2H-1,7-DIOXACYCLOPENT-[CD]-INDENE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
  • [2aR-(4.beta.,4a.alpha.,5.beta.,6.alpha.,7a.alpha.,7b.alpha.)]-4,5-(Diacetoxy)-6-[(acetroxy)methyl]-2a,3,4,5,6,7a,7b-octahydro-2H-1,7-dioxacyclopent[cd]indene
3-O-[2,3,6-TRI-O-ACETYL-4-O-(2,3,4,6-TETRA-O-ACETYL-BETA-D-GALACTOPYRANOSYL)-BETA-D-GLUCOPYRANOSYL]-1,2-DI-O-TETRADECYL-SN-GLYCEROL
3-O-[2,3,6-TRI-O-ACETYL-4-O-(2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSYL)-BETA-D-GLUCOPYRANOSYL]-1,2-DI-O-TETRADECYL-SN-GLYCEROL
ethanone, 1-[2-hydroxy-4-[(2,3,4,6-tetra-O-acetylhexopyranosyl)oxy]phenyl]-2-(4-thiazolyl)-
3-[O-(TETRA-O-ACETYL-BETA-D-GLUCOPYRANOSYL)-(1->4)-O-(TRI-O-ACETYL-BETA-D-GLUCOSYL)-(1->4)-TRI-O-ACETYL-BETA-D-GLUCOSYL]-PROP-1-ENE
1,3,4-TRI-O-ACETYL-6-O-BENZYL-2-O-(TETRA-O-ACETYL-BETA-D-GALACTOPYRANOSYL)-BETA-D-GLUCOPYRANOSIDE
(2R,3S)-2,3-EPOXY-4-HYDROXYBUTYL-HEPTA-O-ACETYL-BETA-CELLOBIOSIDE
O-(2,3,4,6-TETRA-O-ACETYL-BETA-D-GLUCOPYRANOSYL)-(1->1')-(2S,3S,4E)-2-[N-(DIPHENYLMETHYLENE)-AMINO]-3-O-PIVALOYL-4-TRIDECENE-1,3-DIOL
[(4S)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-ETHYL-HEPTA-O-ACETYL-BETA-CELLOBIOSIDE
(2'S)-3'-BENZOYLOXY-2'-MESYLOXYPROPYL-3,4,6-TRI-O-ACETYL-2-ACETYLAMINO-2-DEOXY-BETA-D-GLUCOSIDE
1,2,3,6-TETRA-O-ACETYL-4-O-(3,4,6-TRI-O-ACETYL-2-O-METHYL-ALPHA-D-GLUCOPYRANOSYL)-BETA-D-GLUCOPYRANOSE
Title Journal or Book Year
Iridoids from Carbohydrates via Pauson−Khand Reaction:  Synthesis of Advanced Highly Oxygenated Cyclopentane-Annulated Pyranosides from d-Glucal Derivatives The Journal of Organic Chemistry 1999
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