#14B;(-)-(S)-N,N-DIMETHYLAMINO-S-[(E)-(3R)-1,4-DIMETHYL-3-(PARA-BROMOPHENYL-TRIETHYLSILANYLOXY-METHYL)-PENT-1-ENYL]-PHENYL-SULFOXONIUM-TETRAFLUOROBORATE
Compound with spectra: 1 NMR
![#14B;(-)-(S)-N,N-DIMETHYLAMINO-S-[(E)-(3R)-1,4-DIMETHYL-3-(PARA-BROMOPHENYL-TRIETHYLSILANYLOXY-METHYL)-PENT-1-ENYL]-PHENYL-SULFOXONIUM-TETRAFLUOROBORATE](/api/compound/Et7qLrR8xt6.png?ph=true&h=300&w=458 "#14B;(-)-(S)-N,N-DIMETHYLAMINO-S-[(E)-(3R)-1,4-DIMETHYL-3-(PARA-BROMOPHENYL-TRIETHYLSILANYLOXY-METHYL)-PENT-1-ENYL]-PHENYL-SULFOXONIUM-TETRAFLUOROBORATE")
| SpectraBase Compound ID | Et7qLrR8xt6 |
|---|---|
| InChI | InChI=1S/C28H43BrNO2SSi.BF4/c1-9-34(10-2,11-3)32-28(24-17-19-25(29)20-18-24)27(22(4)5)21-23(6)33(31,30(7)8)26-15-13-12-14-16-26;2-1(3,4)5/h12-22,27-28H,9-11H2,1-8H3;/q+1;-1/b23-21+;/t27-,28-,33?;/m0./s1 |
| InChIKey | BFGNUSMFIISJCX-WWPYKHAWSA-N |
| Mol Weight | 652.5 g/mol |
| Molecular Formula | C28H43BBrF4NO2SSi |
| Exact Mass | 651.199633 g/mol |
| Parent InChIKey | QYTITDASLWUWLU-PCYHAGKNSA-N |
| Enantiomer InChIKey | BFGNUSMFIISJCX-MKPKWGBSSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(t-Butyl)-[(2-isopropyl-1-phenyl-4-[N-(methylphenylsulfon)imidoyl]pent-3-enyl)oxy]dimethylsilane
Ethyl 2,5-dihydro-2-phenyl-4-[(phenylsulfonyl)methylene]furan-3-carboxylate
(1Z)-(3S,4S)-[2,5-Dimethyl-3-phenyl-4-(triethylsilyloxy)-1-hexenyl]-N-methyl-S-(phenylsulfoximine)
Triethyl-[(E,1S,2R)-1-isopropyl-3-methyl-4-(N-methyl-S-phenyl-sulfonimidoyl)-2-phenyl-but-3-enoxy]silane
1-(7'-Bromobicyclo[4.1.0]hept-2'-en-1'-yl)-1-phenylmethanol - trimethylsilyl ether
5-[2-(Toluene-4-sulfonylamino)-phenyl]-furan-2-carboxylic acid ethyl ester
Allyl (5R,6S,8R)-5-tosyloxy-6-methyl-7-oxo-8-[(tert-butyldimethylsilyl)oxy]-8-phenyloct-2(E)-enoate
Methyl (E)-2,2-Dibenzyl-5-phenyl-4-tosyl-3-pentenoate
(-)-(4R,5R)-TRIETHYL-[3-METHYL-4-PHENYL-5-(4-BROMOPHENYL)-4,5-DIHYDRO-FURAN-2-YL]-SILANE
(-)-(7-R,8'-R,8-R)-ACUMICATOLIDE
| Title | Journal or Book | Year |
|---|---|---|
| Asymmetric Synthesis of anti-Homopropargylic Alcohols from Aldehydes and Chiral Sulfonimidoyl Substituted Bis(allyl)titanium Complexes through Generation and Elimination of Novel Chiral Alkylidenecarbene (Dimethylamino)sulfoxonium Ylides | Journal of the American Chemical Society | 2002 |