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(2R*,3R*,5S*)/(2R*,3S*,5R*)-(+/-)-5-[[(1,1-DIMETHYLETHYL)-DIMETHYLSILYL]-OXY]-3-(METHOXYMETHOXY)-8-(PHENYLMETHOXY)-6-OCTYNE-1,2-DIOL

Compound with spectra: 1 NMR

(2R*,3R*,5S*)/(2R*,3S*,5R*)-(+/-)-5-[[(1,1-DIMETHYLETHYL)-DIMETHYLSILYL]-OXY]-3-(METHOXYMETHOXY)-8-(PHENYLMETHOXY)-6-OCTYNE-1,2-DIOL
SpectraBase Compound ID EbZ7RaJ4AQt
InChI InChI=1S/C23H38O6Si/c1-23(2,3)30(5,6)29-20(15-22(21(25)16-24)28-18-26-4)13-10-14-27-17-19-11-8-7-9-12-19/h7-9,11-12,20-22,24-25H,14-18H2,1-6H3/t20-,21?,22-/m0/s1
InChIKey SXEZHMIBXRZKDC-NHNZYLEHSA-N
Mol Weight 438.6 g/mol
Molecular Formula C23H38O6Si
Exact Mass 438.243765 g/mol
Enantiomer InChIKey SXEZHMIBXRZKDC-NHXNGRAPSA-N

View Spectrum of (2R*,3R*,5S*)/(2R*,3S*,5R*)-(+/-)-5-[[(1,1-DIMETHYLETHYL)-DIMETHYLSILYL]-OXY]-3-(METHOXYMETHOXY)-8-(PHENYLMETHOXY)-6-OCTYNE-1,2-DIOL

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
(2S,3R,5R)-5-{[tert-Butyl(dimethyl)silyl]oxy}-7-[(4-methoxybenzyl)oxy]-3-methoxymethoxy-2-methylheptan-1-ol
(4R,6R)-6-(tert-Butyldimethyl-silyloxy)-1-(4-methoxybenzyloxy)-3-methylene-8-trimethylsilyloct-7-yn-4-ol
{[(tert-Butyl)dimethylsilyl]oxy}octyl (RS,E,E)-4-{[(tert-Butyl)dimethylsilyl]oxy}-7,11-dimethyl-13-{[(RS)-tetrahydro-2H-pyran-2-yl]oxy}trideca-7,11-dien-2-ynoate
1.alpha.-(Hydroxymethyl)-2.alpha.-((tert-butyldimethylsilyl)oxy)-4.beta.-((benzyloxy)methyl)cyclohexane
1(eq)-Hydroxy-2(eq)-(T-butyl-dimethyl-siloxy)-4(eq)-(benzyloxy-methyl)-cyclohexane
Bicyclo[9.3.0]-3,7-di(t-butyldimethylsilyloxy)-13-thiono-12,14-dioxa-2,9-tetradecadiyne
(RS,2E,6E,21Z)-10-{[(tert-Butyl)dimethylsilyl]oxy} 3,7-dimethyl-1-{[(RS)-tetrahdydro-2H-pyran-2-yl]oxy}triaconta-2,6,21-trien-11-yn-13-one
(2R,3R,4R)-6-(tert-Butyldimethylsilyl)oxy-2,3-epoxy-4-(methoxymethyl)oxy-1-{[4'-methoxyphenyl)methyl]oxy}hexane
(2s,3s)-3-benzyloxy-4-(tert-butyldimethylsilyloxy)butan-1,2-diol isopropylidene acetal
(2S*,3S*)-2-[3'-(tert-butyldimethylsiloxy)-2'-oxepanyl]-1,2-ethanediol
Title Journal or Book Year
Applications of 5-Endo-trigonal Cyclization:  Construction of Compounds Relevant to the Synthesis of Prostaglandins and Methyl epi-Jasmonate The Journal of Organic Chemistry 1999
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