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(-)-(1S,3S,4S)-3-(4-Bromo-3-methylbut-2-en-1-yl)-1,3-dimethyl-8-methylenebicyclo[2.2.2]oct-5-en-2-one

Compound with spectra: 1 NMR

(-)-(1S,3S,4S)-3-(4-Bromo-3-methylbut-2-en-1-yl)-1,3-dimethyl-8-methylenebicyclo[2.2.2]oct-5-en-2-one
SpectraBase Compound ID D6pdU5OeGit
InChI InChI=1S/C16H21BrO/c1-11(10-17)5-8-16(4)13-6-7-15(3,14(16)18)9-12(13)2/h5-7,13H,2,8-10H2,1,3-4H3/b11-5+/t13-,15+,16-/m1/s1
InChIKey RQIGRXKSNZHSKF-ITKLVJOZSA-N
Mol Weight 309.25 g/mol
Molecular Formula C16H21BrO
Exact Mass 308.077578 g/mol
Enantiomer InChIKey RQIGRXKSNZHSKF-UEFUKBCXSA-N

View Spectrum of (-)-(1S,3S,4S)-3-(4-Bromo-3-methylbut-2-en-1-yl)-1,3-dimethyl-8-methylenebicyclo[2.2.2]oct-5-en-2-one

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
(-)-(1S,3S,4S)-3-(4-Bromo-3-methylbut-2-en-1-yl)-1,3-dimethyl-8-methylenebicyclo[2.2.2]oct-5-en-2-one
(1RS,3RS,4SR)-1,3,4-TRIMETHYL-3-(3'-METHYLBUT-2'-ENYL)-BICYCLO-[2.2.2]-OCT-5-EN-2-ONE
BICYCLO[2.2.2]OCT-5-EN-2-ONE, 1,3,4-TRIMETHYL-3-(3-METHYYL-2-BUTENYL)-
(1RS,3SR,4SR)-1,3,4-TRIMETHYL-3-(3'-METHYLBUT-2'-ENYL)-BICYCLO-[2.2.2]-OCT-5-EN-2-ONE
1,5-Methano-4H-inden-4-one, 1,2,3,3a,5,7a-hexahydro-3a,8,8-trimethyl-
(2R,3R,5S)-5-Isopropenyl-2-{2-[6-methoxy-3,4-dihydro-2H-naphthalen-(1E)-ylidene]-ethyl}-2-methyl-3-vinyl-cyclohexanone
1,2-Naphthalenedicarboxylic acid, 1,5,6,7,8,8a-hexahydro-5,5-dimethyl-, dimethyl ester, trans-(.+-.)-
1,2-NAPHTHALENEDICARBOXYLIC ACID, 1,5,6,7,8,8A-HEXAHYDRO-5,5-DIMETHYL- DIMETHYL ESTER
(3Ab, 5aa,6a,8aa)-4,5,6,6a,7,8-hexahydro-3a,6-dimethyl-cyclopenta(C)pentalen-3(1ah)-one
syn-11-Hydroxy-tetracyclo(6.2.1.0/1,6/.0/4,6/)undec-9-ene
7,7-Dimethyl-2,6-dimethylenetricyclo[6.2.1.0(1,5)]undec-9-ene
Title Journal or Book Year
Chiral synthons from carvone. Part 31.† Enantiospecific total synthesis of (+)-2-pupukeanone and 5-epi-2-pupukeanone Journal of the Chemical Society, Perkin Transactions 1 1998
(-)-(1S,3S,4S)-3-(4-Bromo-3-methylbut-2-en-1-yl)-1,3-dimethyl-8-methylenebicyclo[2.2.2]oct-5-en-2-one
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