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(1,2;5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GULOFURANOS-3-O-YL)-2-[1'-(DIETHYLPHOSPHORYLOXY)-ETYLIDENE]-6-TRIMETHYLSILYL-5-HEXYNOATE

Compound with spectra: 1 NMR

(1,2;5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GULOFURANOS-3-O-YL)-2-[1'-(DIETHYLPHOSPHORYLOXY)-ETYLIDENE]-6-TRIMETHYLSILYL-5-HEXYNOATE
SpectraBase Compound ID CjaEjDhrcsZ
InChI InChI=1S/C27H45O11PSi/c1-11-31-39(29,32-12-2)38-18(3)19(15-13-14-16-40(8,9)10)24(28)33-22-21(20-17-30-26(4,5)35-20)34-25-23(22)36-27(6,7)37-25/h20-23,25H,11-13,15,17H2,1-10H3/b19-18-/t20-,21-,22+,23+,25+/m1/s1
InChIKey CKQRYJFVVMZREY-ZOUQSQCJSA-N
Mol Weight 604.7 g/mol
Molecular Formula C27H45O11PSi
Exact Mass 604.246876 g/mol
Enantiomer InChIKey CKQRYJFVVMZREY-JNKDPPSCSA-N

View Spectrum of (1,2;5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GULOFURANOS-3-O-YL)-2-[1'-(DIETHYLPHOSPHORYLOXY)-ETYLIDENE]-6-TRIMETHYLSILYL-5-HEXYNOATE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent Unknown
(1,2;5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOS-3-O-YL)-2-[1'-(DIETHYLPHOSPHORYLOXY)-ETYLIDENE]-6-TRIMETHYLSILYL-5-HEXYNOATE
(1,2;5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-ALLOFURANOS-3-O-YL)-2-[1'-(DIETHYLPHOSPHORYLOXY)-ETYLIDENE]-6-TRIMETHYLSILYL-5-HEXYNOATE
(1,2:5,6-Di-O-isopropylidene-.alpha.-D-glucofuranos-3-O-yl)-2-[1'-(diethoxyphosphoryloxy)ethylidene]-5-methyl-4-hexenoate
(1,2:5,6-Di-O-isopropylidene-.alpha.-D-glucofuranos-3-O-yl)-2-Acetyl-2-(3'-methylbutenyl)-5-methyl-4-hexenoate
(3aS,5S,6R,6aS)-5-[(S)-2,2-Dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-6-yl 4-(4-oxo-4H-pyrido[1,2-a]pyrimidin-2-yl)butanoate
.alpha.-D-Glucofuranose, 3-O-(2,3,5-O-acetyl-.beta.-D-lyxofuranosyl)-1,2:5,6-DI-O-isopropylidene-
3-O-(1,2:5,6-diisopropylidene-.alpha.,D-glucofuranosyl)-2-fluoro-4,4-dimethyl-2-buten-4-olide
(E)-Pentacarbonyl [3-(1',2' : 5',6'-di-O-isopropylidene-.alpha.-D-glucofuranos-3'-O-yl)-1-ethoxy-3-phenyl-2-propenylidene] chromium
1,2;5,6-Bis(isopropylidene)-3-[O-[3-(3-methyl-2,3-dihydroibenzofuran-3-yl)-2-methylenepropyl]-manno-hexafuranose
(E)-Pentacarbonyl [3-(1',2' : 5',6'-di-O-isopropylidene-.beta.-D-mannofuranosyloxy)-1-ethoxy-3-phenyl-2-propenylidene] tungsten
Title Journal or Book Year
Photochemical Deconjugation of Chiral 3-Methyl-2-butenoates Derived from Carbohydrate-Based Alcohols:  The Influence of the Sugar Backbone on the Facial Diastereoselectivity The Journal of Organic Chemistry 2001
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