(-)-DIBrOMO-(DIETHYL-4,4'-([(1R,2R)-CYClOHEXAN-1,2-DIYL]-DINITRILO)-3,3,3',3'-TETRAMETHYL-4,4'-[(2,3,7,8-TETRAHYDRO-2,2,3,3,7,7,8,8-OCTAMETHYL-11H-DIPYRRIN-1,
Compound with spectra: 1 NMR
![(-)-DIBrOMO-(DIETHYL-4,4'-([(1R,2R)-CYClOHEXAN-1,2-DIYL]-DINITRILO)-3,3,3',3'-TETRAMETHYL-4,4'-[(2,3,7,8-TETRAHYDRO-2,2,3,3,7,7,8,8-OCTAMETHYL-11H-DIPYRRIN-1,](/api/compound/CJJOvRu3uDc.png?ph=true&h=300&w=458 "(-)-DIBrOMO-(DIETHYL-4,4'-([(1R,2R)-CYClOHEXAN-1,2-DIYL]-DINITRILO)-3,3,3',3'-TETRAMETHYL-4,4'-[(2,3,7,8-TETRAHYDRO-2,2,3,3,7,7,8,8-OCTAMETHYL-11H-DIPYRRIN-1,")
| SpectraBase Compound ID | CJJOvRu3uDc |
|---|---|
| InChI | InChI=1S/C39H61N6O4.2BrH.Co/c1-15-48-28(46)22-34(3,4)30-40-24-19-17-18-20-25(24)41-31(35(5,6)23-29(47)49-16-2)45-33-39(13,14)37(9,10)27(43-33)21-26-36(7,8)38(11,12)32(42-26)44-30;;;/h21,24-25H,15-20,22-23H2,1-14H3;2*1H;/q-1;;;+3/p-2/t24-,25-;;;/m1.../s1 |
| InChIKey | UTGFJIGQJFKYAY-ZDASDOCVSA-L |
| Mol Weight | 896.7 g/mol |
| Molecular Formula | C39H61Br2CoN6O4 |
| Exact Mass | 894.245299 g/mol |
| Parent InChIKey | VTYAZHKRCYYFSC-JWQCQUIFSA-L |
| Enantiomer InChIKey | UTGFJIGQJFKYAY-FQFBWUQZSA-L |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
Methyl 2.beta.-(2'-(m-isopropyl-phenyl)ethyl)-1.beta.,3.alpha.-dimethyl-cyclohexanecarboxylate (so name and structure in Anderson & Botto) but MS (intense fragement at m/z = 187) and RT suggest 2.alpha.-epimer instead, with Reg. No. 19556-80-0? a methyl seco-dehydro-abietate
Diethyl 4,4''-{[(1R,2R)-cyclohexane-1,2-diyl]dinitrilo-3,3,3',3'-tetramethyl-4,4'-[(2",3",7",8"-tetrahydro-2",2",3",3",7",7",8',8'-octamethyl-11"H-dipyrrin-1",9"-diylidene)-dinitrilo]-bis[butanoato](1-)cobalt(III)
{(4a,5,6,7,7a-.eta.)-4-(2",2"-Dimethyl-1",3"-dioxolan-4"-yl)-3a,5,8,8a-tetrahydro-2,2-dimethyl-4H-indeno[5,6-d]-1,3-dioxol-5-yl}-{(4',5',6',7',7a'-.eta.)-5'-(chloromercurio)-4'-(2"',2"'-dimethyl-1'",3'"-dioxolan-4"'-yl}-3a',5',8',8a'-tetrahydro-2',2'-dimethyl-4H-indeno5,6-d]-1',3'-dioxol-5'-yl}- iron (II)
13',16':18',21'-dietheno-1,1''-diethyl-3',14',20',31'-tetramethyldispiro[piperidine-4,17'-[5,12,22,29]tetraoxa[37,40,41]triazatetracyclo[31.13.1.0.(4,45).0(30,35)]heptatetraconta-1',3',13',15',18',20',30',34',35',45'-decaene-47',4''-piperidine]-38',42'-dione
2-Propenoic acid, 3-phenyl-, 1,1a,1b,1c,2a,3,3a,4,6a,6b,7,8-dodecahydro-3a,6b-dihydroxy-1,1,5,7-tetramethyl-4-oxo-2a-[[(1-oxo-3-phenyl-2-propenyl)oxy]methyl]-8aH-cyclopropa[5',6']benz[1',2':7,8]az uleno[5,6-b]oxirene-8,8a-diyl ester, [1aR-(1a.alpha.,1b.beta.,1c.beta.,2a.beta.,3a.beta.,6a.alpha.,6b.alpha.,7.alpha.,8.beta.,8a.alpha.)]-
4H-9,12:15,18-Dietheno-28,31-imino-26,23-methenopyrrolo[2,3-n][1,19,6]dioxaazacyclohentriacontine-6,21,24(5H,22H,25H)-trione, 30-ethyl-2-[(3-ethyl-1,5-dihydro-4-methyl-5-oxo-2H-pyrrol-2-ylidene)methyl]-8,13,14,19-tetrahydro-3,29,34-trimethyl-, (Z,Z,Z)-
38-(3,5-Dimethylphenyl)-7,8,19,20,28,29,35,36-octahydro-6H,10H,16H,32H,34H-59:17,21-dimethano-11,15-metheno-1,2,5-[1',3']pyrimidino-5H,27H-dibenzo[b,u][1,23,4,8,16,20]dioxatetraazacyclohexacosine-32,37,39-trione
38-(3,5-Dimethylphenyl)-7,8,19,20,28,29,35,36-octahydro-6H,10H,16H,32H,34H-59:17,21-dimethano-11,15-metheno-1,2,5-[1',3']pyrimidino-5H,27H-dibenzo[b,u][1,23,4,8,16,20]dioxatetraazcyclohexacosine-32,37,39-trione
6H,13H-5,13:6,12-Dietheno-5a,12a-(methaniminomethano)-1H,5H,8H,12H-[1,2,4]triazolo[1,2-a][1,2,4]triazolo[1',2':1,2]pyridazino[4,5-d]pyridazine-18-acetic acid, 2,3,9,10-tetrahydro-.alpha.-(2-methylpropyl)-1,3,8,10,17,19-hexaoxo-2,9-diphenyl-, hexyl ester, stereoisomer
(2S,5S*,7S*,9S,1-S,12R,13Z,15R)-2-[(2R,5R,6S)-5-Benzyloxy-5-ethyl-6-methyltetrahydropyran-2-yl]-9-[(R)-1-ethyl-2-oxobutyl]-15-(4-methoxybenzyloxy)-2,10,12-trimethyl-1,6,8-trioxadispiro[4.1.3.5]pentadec-13-ene
| Title | Journal or Book | Year |
|---|---|---|
| Synthese chiraler Kobalt-Komplexe mit planoid-tetradentatem Ligand-System | Helvetica Chimica Acta | 1993 |