2-[(1-PHENYLSULFONYL)-TRYPTOPHYL]-4-(TERT.-BUTOXYCARBONYL)-5-BETA-CYANO-7-(TRIMETHYLSILOXY)-1,2,5,8,9,10-HEXAHYDROISOQUINOLINE;MAJOR-EPIMER
Compound with spectra: 1 NMR
![2-[(1-PHENYLSULFONYL)-TRYPTOPHYL]-4-(TERT.-BUTOXYCARBONYL)-5-BETA-CYANO-7-(TRIMETHYLSILOXY)-1,2,5,8,9,10-HEXAHYDROISOQUINOLINE;MAJOR-EPIMER](/api/compound/C26Jp7kNQyY.png?ph=true&h=300&w=458 "2-[(1-PHENYLSULFONYL)-TRYPTOPHYL]-4-(TERT.-BUTOXYCARBONYL)-5-BETA-CYANO-7-(TRIMETHYLSILOXY)-1,2,5,8,9,10-HEXAHYDROISOQUINOLINE;MAJOR-EPIMER")
| SpectraBase Compound ID | C26Jp7kNQyY |
|---|---|
| InChI | InChI=1S/C34H41N3O5SSi/c1-34(2,3)41-33(38)30-23-36(21-26-19-27(42-44(4,5)6)18-25(20-35)32(26)30)17-16-24-22-37(31-15-11-10-14-29(24)31)43(39,40)28-12-8-7-9-13-28/h7-15,18,22-23,25-26,32H,16-17,19,21H2,1-6H3/t25-,26+,32+/m0/s1 |
| InChIKey | POKKXAGEVUBVSB-NSTRGFCRSA-N |
| Mol Weight | 631.9 g/mol |
| Molecular Formula | C34H41N3O5SSi |
| Exact Mass | 631.253619 g/mol |
| Enantiomer InChIKey | POKKXAGEVUBVSB-IWITZMJESA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
1H-Indole, 3-(1,3,3a,4,7,7a-hexahydro-6-methyl-1,3-dioxo-4-isobenzofuranyl)-1-(phenylsulfonyl)-, (3a.alpha.,4.beta.,7a.alpha.)-(.+-.)-
4-Cyclohexene-1,2-dicarboxylic acid, 5-methyl-3-[1-[(4-methylphenyl)sulfonyl]-1H-indol-3-yl]-, dimethyl ester, (1.alpha.,2.alpha.,3.alpha.)-(.+-.)-
4,5-Dihydro-4-(p-chlorophenyl)-6-(N-benzenesulphonyl-1H-indol-3-yl)-2H-indazol-3(3aH)-one
2.alpha.,5.alpha.,15.alpha.-tris(2',4'-Dioxo-2',5'-yclohexadien-2'-yl)-10,15-dihydro-5H-diindeno[1,2-a : 1',2'-c]fluorene
2.alpha.,5.alpha.,15.beta.-tris(2',4'-Dioxo-2',5'-yclohexadien-2'-yl)-10,15-dihydro-5H-diindeno[1,2-a : 1',2'-c]fluorene
7-[(2-CARBOXYPHENYL)-THIO]-1-CYCLOPROPYL-6-FLUORO-8-NITRO-4-OXO-1,4-DIHYDROQUINOLINE-3-CARBOXYLIC-ACID
5ALPHAH-2BETA,4BETA-EPOXY-3ALPHA-HYDROXYGUAIA-1(10),11(13)-DIEN-6ALPHA,12-OLIDE
4-(11-keto-3-methyl-8,9,10,12-tetrahydro-7H-benzo[b][4,7]phenanthrolin-12-yl)benzoic acid methyl ester
PREMNAODOROSIDE_C;DIASTEREOMER_2
(2R)-5-(6-bromanyl-1H-indol-3-yl)-2-[6-bromanyl-1-(4-methylphenyl)sulfonyl-indol-3-yl]-2,3-dihydro-1H-pyrazin-6-one
| Title | Journal or Book | Year |
|---|---|---|
| Formal total synthesis of deserpidine demonstrating a versatile amino-Claisen rearrangement/Wenkert cyclization strategy for the preparation of functionalized yohimbane ring systems | Journal of the American Chemical Society | 1990 |